Recent Advances in the Gold-Catalysed Low-Temperature Water-Gas Shift Reaction

被引:32
作者
Carter, James H. [1 ]
Hutchings, Graham J. [1 ]
机构
[1] Cardiff Univ, Cardiff Catalysis Inst, Sch Chem, Main Bldg,Pk Pl, Cardiff CF10 3AT, S Glam, Wales
来源
CATALYSTS | 2018年 / 8卷 / 12期
基金
欧洲研究理事会;
关键词
gold; water-gas shift; hydrogen; supported nanoparticles; ceria; PURE HYDROGEN-PRODUCTION; MOLYBDENUM CARBIDE; CERIA-ALUMINA; IN-SITU; GOLD/CERIA-ZIRCONIA; AU-CEO2; CATALYSTS; OXYGEN VACANCIES; AU; WGS; PD;
D O I
10.3390/catal8120627
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The low-temperature water gas shift reaction (LTS: CO + H2O.=s CO2 + H-2) is a key step in the purification of H-2 reformate streams that feed H-2 fuel cells. Supported gold catalysts were originally identified as being active for this reaction twenty years ago, and since then, considerable advances have been made in the synthesis and characterisation of these catalysts. In this review, we identify and evaluate the progress towards solving the most important challenge in this research area: the development of robust, highly active catalysts that do not deactivate on-stream under realistic reaction conditions.
引用
收藏
页数:15
相关论文
共 50 条
[31]   Application of Au/TiO2 catalysts in the low-temperature water-gas shift reaction [J].
Perez, Patricia ;
Soria, Miguel A. ;
Carabineiro, Sonia A. C. ;
Maldonado-Hodar, Francisco J. ;
Mendes, Adelio ;
Madeira, Luis M. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (08) :4670-4681
[32]   Plasmonic Cu Nanoparticles for the Low-temperature Photo-driven Water-gas Shift Reaction [J].
Zhao, Jiaqi ;
Bai, Ya ;
Li, Zhenhua ;
Liu, Jinjia ;
Wang, Wei ;
Wang, Pu ;
Yang, Bei ;
Shi, Run ;
Waterhouse, Geoffrey I. N. ;
Wen, Xiao-Dong ;
Dai, Qing ;
Zhang, Tierui .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 62 (13)
[33]   Trends in low-temperature water-gas shift reactivity on transition metals [J].
Schumacher, N ;
Boisen, A ;
Dahl, S ;
Gokhale, AA ;
Kandoi, S ;
Grabow, LC ;
Dumesic, JA ;
Mavrikakis, M ;
Chorkendorff, I .
JOURNAL OF CATALYSIS, 2005, 229 (02) :265-275
[34]   Gold-based catalysts for the water-gas shift reaction: Active sites and reaction mechanism [J].
Rodriguez, Jose A. .
CATALYSIS TODAY, 2011, 160 (01) :3-10
[35]   Low-Temperature Water-Gas Shift Reaction over Au/ZrO2 Catalysts Using Hydrothermally Synthesized Zirconia as Supports [J].
Zhang Yanjie ;
Zhan Yingying ;
Cao Yanning ;
Chen Chongqi ;
Lin Xingyi ;
Zheng Qi .
CHINESE JOURNAL OF CATALYSIS, 2012, 33 (02) :230-236
[36]   Charge Polarization at a Au-TiC Interface and the Generation of Highly Active and Selective Catalysts for the Low-Temperature Water-Gas Shift Reaction [J].
Rodriguez, Jose A. ;
Ramirez, Pedro J. ;
Giacomo Asara, Gian ;
Vines, Francesc ;
Evans, Jaime ;
Liu, Ping ;
Ricart, Josep M. ;
Illas, Francesc .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (42) :11270-11274
[37]   Counting Au catalytic sites for the water-gas shift reaction [J].
Shekhar, Mayank ;
Wang, Jun ;
Lee, Wen-Sheng ;
Akatay, M. Cem ;
Stach, Eric A. ;
Delgass, W. Nicholas ;
Ribeiro, Fabio H. .
JOURNAL OF CATALYSIS, 2012, 293 :94-102
[38]   Rate Expression for Water-Gas Shift over a Gold/Ferrochrome Catalyst [J].
Vajani, Gaurav N. ;
Shea Lerk Ng ;
Lund, Carl R. F. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (18) :10493-10499
[39]   Dispersion of Au entities over Mo2N and MoC for the low-temperature water-gas shift reaction [J].
Guo, Peiyao ;
Jin, Chuanchuan ;
Han, Shaobo ;
Zhou, Yan ;
Shen, Wenjie .
CATALYSIS SCIENCE & TECHNOLOGY, 2024, 14 (16) :4542-4549
[40]   Quantification and optimization of platinum-molybdenum carbide interfacial sites to enhance low-temperature water-gas shift reaction [J].
Li, Ruiying ;
Shang, Jingyuan ;
Wang, Fei ;
Lu, Qing ;
Yan, Hao ;
Tuo, Yongxiao ;
Liu, Yibin ;
Feng, Xiang ;
Chen, Xiaobo ;
Chen, De ;
Yang, Chaohe .
NATURE COMMUNICATIONS, 2025, 16 (01)