Facile and green fabrication of silver nanoparticles on a polyoxometalate for Li-ion battery

被引：44
作者：
Eren, Tanju [1 ]
Atar, Necip [1 ]
Yola, Mehmet Lutfi [2 ]
Karimi-Maleh, Hassan [3 ]
Colak, Alper Tolga [4 ]
Olgun, Asim [4 ]
机构：
[1] Pamukkale Univ, Dept Chem Engn, Denizli, Turkey
[2] Sinop Univ, Dept Met & Mat Engn, Sinop, Turkey
[3] Grad Univ Adv Technol, Dept Chem, Kerman, Iran
[4] Dumlupinar Univ, Dept Chem, Kutahya, Turkey
来源：
IONICS | 2015年 / 21卷 / 08期
关键词：
Polyoxometalate; Silver nanoparticle; Li-ion battery; Anode; Characterization; WALLED CARBON NANOTUBES; CATHODE MATERIAL; PASTE ELECTRODE; LITHIUM; STORAGE; NANOSHEETS; QUERCETIN; COMPOSITE; SENSOR;
D O I：
10.1007/s11581-015-1409-z
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In the present study, we report the green and one-pot synthesis of silver nanoparticles (AgNPs) on as-prepared novel polyoxometalate {[Ni-2,Ni-5(Hpen)(4)(PW9O34)] center dot 5H(2)O} (POM) without any reducing agent and its application as improved anode material for lithium-ion batteries (LIBs). The structure of the AgNPs involved POM (AgNPs/POM) nanocomposite was characterized by transmission electron microscopy, scanning electron microscopy, and X-ray photoelectron spectroscopy. The synthesized POM was also characterized by elemental analysis and thermal analysis. The electrochemical performances of the POM, AgNPs, and AgNPs/POM composites were measured for charge/discharge specific capacities at different current rates in CR2032 coin-type cells. The prepared AgNPs/POM composite showed a high specific gravimetric capacity of about 1760 mAh g(-1) and long-term cycle stability.
引用
收藏
页码：2193 / 2199
页数：7
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