Recent Advances in the Chemistry of N-Heterocyclic-Carbene-Functionalized Metal-Nanoparticles and Their Applications

被引：56

作者：

An, Yuan-Yuan ^{[1
]}

Yu, Jian-Gang ^{[1
,2
]}

Han, Ying-Feng ^{[1
,3
]}

机构：

[1] Northwest Univ, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Xian 710127, Shaanxi, Peoples R China

[2] Quzhou Univ, Coll Chem & Mat Engn, Quzhou 324000, Zhejiang, Peoples R China

[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2019年 / 37卷 / 01期

关键词：

carbenes; ligand design; materials science; nanoparticles; catalytic application; STABILIZED RUTHENIUM NANOPARTICLES; PROTECTED GOLD NANOPARTICLES; SIZE-CONTROLLED SYNTHESIS; PALLADIUM NANOPARTICLES; SURFACE FUNCTIONALIZATION; ALKYNE SEMIHYDROGENATION; SELECTIVE HYDROGENATION; CATALYZED REACTIONS; IMIDAZOLIUM SALTS; AU NANOPARTICLES;

D O I：

10.1002/cjoc.201800450

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-nanoparticles (M-NPs) have been widely applied in catalysis, imaging, sensing and medicine. One particularly active area of this research is the modification of the surface of the nanoparticles to prevent aggregation through the coordination of ligands. N-Heterocyclic carbenes (NHCs) have emerged as suitable ligands for this purpose due to their affinity to the metals and their strongly electron donating nature. A number of rationally designed NHC-modified M-NPs have been developed using strategies based on metal complex decomposition and ligand exchange. Herein, NHC-stabilized M-NPs based on a range of transition metals, especially the recent advances, were summarized.

引用

页码：76 / 87

页数：12

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