Enhanced Electrochemical performance at high temperature of Cobalt Oxide/Reduced Graphene Oxide Nanocomposites and its application in lithium-ion batteries

被引:36
|
作者
Mussa, Yasmin [1 ]
Ahmed, Faheem [1 ]
Abuhimd, Hatem [2 ]
Arsalan, Muhammad [3 ]
Alsharaeh, Edreese [1 ]
机构
[1] Alfaisal Univ, Coll Sci & Gen Studies, POB 50927, Riyadh 11533, Saudi Arabia
[2] King Abdulaziz City Sci & Technol, Natl Nanotechnol Ctr, POB 6086, Riyadh 11442, Saudi Arabia
[3] Saudi Aramco, EXPEC Adv Res Ctr, POB 5000, Dhahran 31311, Saudi Arabia
关键词
MICROWAVE-ASSISTED SYNTHESIS; ANODE MATERIALS; CO3O4; NANOPARTICLES; HYDROTHERMAL SYNTHESIS; COMPOSITE; FACILE;
D O I
10.1038/s41598-018-37032-5
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
We report a microwave irradiation method for the preparation of reduced graphene oxide (RGO) based Co3O4 nanocomposites as anodes for lithium-ion (li-ion) batteries. The Co3O4/RGO nanocomposites displayed good electrochemical behavior as anodic materials for li-ion batteries when compared to pure Co3O4. The Co3O4/RGO nanocomposites with low RGO content resulted in stable electrochemical performance with 100% coulombic efficiency at a high current density of 500 mA/g for 50 cycles. The enhanced capacity of the Co3O4/RGO nanocomposites is due to the incorporation of RGO, which resulted in a four times larger surface area than that of Co3O4. This increased surface area could facilitate the absorption of more lithium ions, resulting in excellent electrochemical performance. Interestingly, the novelty of this work is that the designed li-ion batteries showed stable electrochemical performance even at a high temperature of 100 degrees C, which might be useful for rechargeable battery applications in a wide temperature range.
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页数:10
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