Luminescence of praseodymium (III) chelates from two excited states (3P0 and 1D2) and its dependence on ligand triplet state energy

被引：100

作者：

Voloshin, AI ^{[1
]}

Shavaleev, NM ^{[1
]}

Kazakov, VP ^{[1
]}

机构：

[1] Russian Acad Sci, Ufa Sci Ctr, Inst Organ Chem, Ufa 450054, Russia

来源：

JOURNAL OF LUMINESCENCE | 2001年 / 93卷 / 03期

关键词：

praseodymium; beta-diketonate complexes; carboxylate complexes;

D O I：

10.1016/S0022-2313(01)00194-6

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

The praseodymium (III) beta -diketonate and carboxylate chelates emit visible and infrared luminescence in organic solutions at room temperature. Depending on the position of triplet level of the ligand the ff-emission of Pr3+ was observed either from two excited states (P-3(0) and D-1(2)) at 490, 605, 610, 645, 890 and 1060 nm or from the D-1(2) State only at 605, 890 and 1060 nm. For all chelates studied, the emission has low quantum yield, e.g. <0.2% for D-1(2)-luminescence of Pr(TTA)(3). 2H(2)O in DMSO. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：199 / 204

页数：6

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