Synthesis and crystal structures of bis(1-{(E)-2-pyridinylmethylidene}-semicarbazone)iron(II) and copper(II) diperchlorate monohydrates

被引：17
作者：
Garbelini, Ellery R. [1 ]
Horner, Manfredo [2 ]
Behm, Mariana Boneberger [2 ]
Evans, David J. [3 ]
Nunes, Fabio S. [1 ]
机构：
[1] Univ Fed Parana, Dept Quim, BR-81531990 Curitiba, Parana, Brazil
[2] Univ Fed Santa Maria, Dept Quim, BR-97119900 Santa Maria, RS, Brazil
[3] John Innes Ctr Plant Sci Res, Dept Biol Chem, Norwich NR4 7UH, Norfolk, England
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2008年 / 634卷 / 10期
基金：
英国生物技术与生命科学研究理事会;
关键词：
iron; copper; semicarbazones; perchlorates; crystal structures; electrochemical properties;
D O I：
10.1002/zaac.200800169
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The pyridine-2-carbaldehyde semicarbazone ligand (HL) reacts with iron(II) and copper(II) perchlorates in boiling ethanol to yield red-violet [Fe(II)(HL)(2)](ClO(4))(2)center dot H(2)O(1) and light-green crystals [Cu(II)(HL)(2)](ClO(4))(2)center dot H(2)O(2). The crystals are triclinic with the metal ions in an octahedral environment, coordinated to two nitrogen and one oxygen-donor atom from HL. Electronic, magnetic and electrochemical properties are presented as well.
引用
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页码：1801 / 1806
页数：6
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