Light-Orchestrated Macromolecular "Accordions": Reversible Photoinduced Shrinking of Rigid-Rod Polymers

被引：72
作者：
Bleger, David [1 ]
Liebig, Tobias [2 ]
Thiermann, Raphael [3 ]
Maskos, Michael [3 ]
Rabe, Juergen P. [2 ]
Hecht, Stefan [1 ]
机构：
[1] Humboldt Univ, Dept Chem, D-12489 Berlin, Germany
[2] Humboldt Univ, Dept Phys, D-12489 Berlin, Germany
[3] BAM Bundesanstalt Mat Forsch & Prufung, D-12205 Berlin, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 52期
关键词：
aggregation; azo compounds; nanostructures; photochromism; polymers; DENDRIMERS; BACTERIORHODOPSIN; PHOTOMODULATION; ENCAPSULATION; CATALYSTS;
D O I：
10.1002/anie.201106879
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Light can play: Irradiation causes dramatic changes in the shape of rigid-rod polymers incorporating azobenzene photochromes in the main chain. The embedded photoswitches act as hinges, which upon light-induced isomerization lead to reversible shrinking and stretching of the polymer backbone (see scheme), resembling light-orchestrated macromolecular accordions. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：12559 / 12563
页数：5
相关论文
共 61 条
[1]   Photoregulated Release of Caged Anticancer Drugs from Gold Nanoparticles [J].
Agasti, Sarit S. ;
Chompoosor, Apiwat ;
You, Chang-Cheng ;
Ghosh, Partha ;
Kim, Chae Kyu ;
Rotello, Vincent M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (16) :5728-+
[2]  
[Anonymous], 2008, ANGEW CHEM INT EDIT
[3]   Toward photoswitchable dendritic hosts.: Interaction between azobenzene-functionalized dendrimers and eosin [J].
Archut, A ;
Azzellini, GC ;
Balzani, V ;
De Cola, L ;
Vögtle, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (47) :12187-12191
[4]   Catalysts for Suzuki-Miyaura coupling processes: Scope and studies of the effect of ligand structure [J].
Barder, TE ;
Walker, SD ;
Martinelli, JR ;
Buchwald, SL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (13) :4685-4696
[5]   Playing nature's game with artificial muscles [J].
Baughman, RH .
SCIENCE, 2005, 308 (5718) :63-65
[6]   Toward optomechanics: Maximizing the photodeformation of individual molecules [J].
Bleger, David ;
Yu, Zhilin ;
Hecht, Stefan .
CHEMICAL COMMUNICATIONS, 2011, 47 (45) :12260-12266
[7]   Electronic Decoupling Approach to Quantitative Photoswitching in Linear Multiazobenzene Architectures [J].
Bleger, David ;
Dokic, Jadranka ;
Peters, Maike V. ;
Grubert, Lutz ;
Saalfrank, Peter ;
Hecht, Stefan .
JOURNAL OF PHYSICAL CHEMISTRY B, 2011, 115 (33) :9930-9940
[8]   Optically healable supramolecular polymers [J].
Burnworth, Mark ;
Tang, Liming ;
Kumpfer, Justin R. ;
Duncan, Andrew J. ;
Beyer, Frederick L. ;
Fiore, Gina L. ;
Rowan, Stuart J. ;
Weder, Christoph .
NATURE, 2011, 472 (7343) :334-U230
[9]   Photochemical and electronic properties of conjugated bis(azo) compounds: An experimental and computational study [J].
Cisnetti, F ;
Ballardini, R ;
Credi, A ;
Gandolfi, MT ;
Masiero, S ;
Negri, F ;
Pieraccini, S ;
Spada, GP .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (08) :2011-2021
[10]  
Coleman AC, 2011, NAT NANOTECHNOL, V6, P547, DOI [10.1038/NNANO.2011.120, 10.1038/nnano.2011.120]
1234567