Novel synthesis method of CO-Tolerant PtRu-MoOx nanoparticles:: Structural characteristics and performance for methanol electrooxidation

被引：105

作者：

Martinez-Huerta, M. V. ^{[1
]}

Rodriguez, J. L. ^{[1
]}

Tsiouvaras, N. ^{[2
]}

Pena, M. A. ^{[2
]}

Fierro, J. L. G. ^{[2
]}

Pastor, E. ^{[1
]}

机构：

[1] Univ La Laguna, Dept Quim Fis, Tenerife 38071, Spain

[2] CSIC, Inst Catalisis & Petr Quim, Madrid 28049, Spain

来源：

CHEMISTRY OF MATERIALS | 2008年 / 20卷 / 13期

关键词：

D O I：

10.1021/cm703047p

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Carbon-supported PtRu-MoOx nanoparticles with significant CO tolerance were prepared by a new two-step procedure: in the first step, molybdenum oxide was deposited on a carbon substrate (MoOx/C) by impregnation, and in the second one, Pt and Ru were incorporated following a colloidal method with NaHSO3. The composition, particle size, and crystallinity of the catalysts were determined by X-ray analytical methods (X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and total-reflection X-ray fluorescence (TXRF)), transmission electron microscopy (TEM), and thermogravimetry (TG). Conventional electrochemical techniques such as cyclic voltammetry (CV) and chronoamperometry were applied in combination with spectroscopic methods adapted to the electrochemical systems for in situ studies, such as Fourier transform infrared spectroscopy (FTIRS) and differential electrochemical mass spectrometry (DEMS). The results of this work are highly encouraging, as it is proved that a reduction of the amount of precious metals Pt and Ru is possible in parallel with a significant increase of CO tolerance in comparison with commercial catalysts.

引用

页码：4249 / 4259

页数：11

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