Solvation and Stabilization of Metallic Nanoparticles in Ionic Liquids

被引：121
|
作者：
Pensado, Alfonso S. [1 ,2 ]
Padua, Agilio A. H. [1 ,2 ]
机构：
[1] Univ Blaise Pascal Clermont Ferrand, Lab Thermodynam & Interact Mol, F-63171 Aubiere, France
[2] CNRS, F-63171 Aubiere, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 37期
关键词：
ionic liquids; molecular interactions; molecular simulations; nanoparticles; solvation; SIZE-DEPENDENT FORMATION; GAUSSIAN-BASIS SETS; DISSOCIATIVE CHEMISORPTION; RUTHENIUM NANOPARTICLES; ATOMS LI; SURFACE; ORGANIZATION;
D O I：
10.1002/anie.201103096
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Not thick-skinned: The solvation of a metallic nanoparticle in the ionic liquid [C 4C 1im][Ntf 2] was investigated by molecular simulation with a specific interaction potential. The interfacial layer of ionic liquid is only one ion thick, and thus excludes a stabilization mechanism based on an electrostatic double layer. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：8683 / 8687
页数：5
相关论文
共 50 条
  • [1] Interaction Energies of Ionic Liquids with Metallic Nanoparticles: Solvation and Stabilization Effects
    Podgorsek, Ajda
    Pensado, Alfonso S.
    Santini, Catherine C.
    Gomes, Margarida F. Costa
    Padua, Agilio A. H.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (07): : 3537 - 3547
  • [2] Solvation of metallic nanoparticles in ionic liquids: An experimental and computational study
    Pensado, Alfonso S.
    Podgorsek, Ajda
    Campbel, Paul
    Gomes, Margarida F. Costa
    Santini, Catherine C.
    Padua, Agilio A. H.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 239
  • [3] Solvation in Ionic Liquids with Polymer-Grafted Nanoparticles
    Liu, Siqi
    Walton, Mia
    Tarakina, Nadezda, V
    Akcora, Pinar
    JOURNAL OF PHYSICAL CHEMISTRY B, 2020, 124 (23): : 4843 - 4850
  • [4] Rationalization of Solvation and Stabilization of Palladium Nanoparticles in Imidazolium-Based Ionic Liquids by DFT and Vibrational Spectroscopy
    Katsyuba, Sergey A.
    Zvereva, Elena E.
    Yan, Ning
    Yuan, Xiao
    Kou, Yuan
    Dyson, Paul J.
    CHEMPHYSCHEM, 2012, 13 (07) : 1781 - 1790
  • [5] Ionic Liquids for the Synthesis and Stabilization of Metal Nanoparticles
    Janiak, Christoph
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2013, 68 (10): : 1059 - 1089
  • [6] Effects of Ionic Liquids on the Stabilization Process of Gold Nanoparticles
    Khavani, Mohammad
    Mehranfar, Aliyeh
    Mofrad, Mohammad R. K.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2022, 126 (46): : 9617 - 9631
  • [7] Transition metal nanoparticles in ionic liquids: Synthesis and stabilization
    Verma, Chandrabhan
    Ebenso, Eno E.
    Quraishi, M. A.
    JOURNAL OF MOLECULAR LIQUIDS, 2019, 276 : 826 - 849
  • [8] Solvation in molecular ionic liquids
    Shim, Y
    Duan, JS
    Choi, MY
    Kim, HJ
    JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (13): : 6411 - 6414
  • [9] Structure and solvation in ionic liquids
    Hardacre, Christopher
    Holbrey, John D.
    Nieuwenhuyzen, Mark
    Youngs, Tristan G. A.
    ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (11) : 1146 - 1155
  • [10] Solvation dynamics in ionic liquids
    Corcelli, Steven A.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
12345