Surface Oxygen-Assisted Pd Nanoparticle Catalysis for Selective Oxidation of Silanes to Silanols

被引：55

作者：

Shimizu, Ken-ichi ^{[1
]}

Kubo, Takahiro ^{[2
]}

Satsuma, Atsushi ^{[2
]}

机构：

[1] Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido 0010021, Japan

[2] Nagoya Univ, Grad Sch Engn, Dept Mol Design & Engn, Nagoya, Aichi 4648603, Japan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 08期

关键词：

heterogeneous catalysis; nanoparticles; oxidation; palladium; silanols; CHEMICAL-COMPOSITION; HYDROLYTIC OXIDATION; ALLYLIC ALCOHOLS; WATER; ORGANOSILANES; EFFICIENT; REACTIVITY; PALLADIUM; PD(111); DECOMPOSITION;

D O I：

10.1002/chem.201103088

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Just add O 2: Based on the fact that an oxygen-adsorbed Pd metal surface shows higher reactivity for water dissociation than a clean Pd surface, carbon-supported Pd nanoparticles (NPs) with surface oxygen atoms were developed as a highly effective and reusable heterogeneous catalyst for selective oxidation of silanes to silanols with water as a green oxidant (see figure). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2226 / 2229

页数：4

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