Surface Oxygen-Assisted Pd Nanoparticle Catalysis for Selective Oxidation of Silanes to Silanols

被引：55
作者：
Shimizu, Ken-ichi [1 ]
Kubo, Takahiro [2 ]
Satsuma, Atsushi [2 ]
机构：
[1] Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido 0010021, Japan
[2] Nagoya Univ, Grad Sch Engn, Dept Mol Design & Engn, Nagoya, Aichi 4648603, Japan
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 08期
关键词：
heterogeneous catalysis; nanoparticles; oxidation; palladium; silanols; CHEMICAL-COMPOSITION; HYDROLYTIC OXIDATION; ALLYLIC ALCOHOLS; WATER; ORGANOSILANES; EFFICIENT; REACTIVITY; PALLADIUM; PD(111); DECOMPOSITION;
D O I：
10.1002/chem.201103088
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Just add O 2: Based on the fact that an oxygen-adsorbed Pd metal surface shows higher reactivity for water dissociation than a clean Pd surface, carbon-supported Pd nanoparticles (NPs) with surface oxygen atoms were developed as a highly effective and reusable heterogeneous catalyst for selective oxidation of silanes to silanols with water as a green oxidant (see figure). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：2226 / 2229
页数：4
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