Recent Advancements in Polysulfone Based Membranes for Fuel Cell (PEMFCs, DMFCs and AMFCs) Applications: A Critical Review

被引：59

作者：

Vinodh, Rajangam ^{[1
]}

Atchudan, Raji ^{[2
]}

Kim, Hee-Je ^{[3
]}

Yi, Moonsuk ^{[1
]}

机构：

[1] Pusan Natl Univ, Dept Elect Engn, Busan 46241, South Korea

[2] Yeungnam Univ, Dept Chem Engn, Gyongsan 38541, South Korea

[3] Pusan Natl Univ, Dept Elect & Comp Engn, Busan 46241, South Korea

来源：

POLYMERS | 2022年 / 14卷 / 02期

关键词：

polysulfone; polymer electrolyte membrane; DMFCs; AMFCs; sulfonation; Nafion(TM); fillers; inorganic; organic hybrid membranes; ANION-EXCHANGE MEMBRANES; ENHANCED PROTON CONDUCTIVITY; METAL-ORGANIC FRAMEWORK; CROSS-LINKED STRUCTURE; COMPOSITE MEMBRANES; SULFONATED POLYSULFONE; ALKALINE MEMBRANE; LOW-HUMIDITY; ELECTROLYTE MEMBRANE; PHOSPHONIC ACID;

D O I：

10.3390/polym14020300

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In recent years, ion electrolyte membranes (IEMs) preparation and properties have attracted fabulous attention in fuel cell usages owing to its high ionic conductivity and chemical resistance. Currently, perfluorinatedsulfonicacid (PFSA) membrane has been widely employed in the membrane industry in polymer electrolyte membrane fuel cells (PEMFCs); however, Nafion(TM) suffers reduced proton conductivity at a higher temperature, requiring noble metal catalyst (Pt, Ru, and Pt-Ru), and catalyst poisoning by CO. Non-fluorinated polymers are a promising substitute. Polysulfone (PSU) is an aromatic polymer with excellent characteristics that have attracted membrane scientists in recent years. The present review provides an up-to-date development of PSU based electrolyte membranes and its composites for PEMFCs, alkaline membrane fuel cells (AMFCs), and direct methanol fuel cells (DMFCs) application. Various fillers encapsulated in the PEM/AEM moiety are appraised according to their preliminary characteristics and their plausible outcome on PEMFC/DMFC/AMFC. The key issues associated with enhancing the ionic conductivity and chemical stability have been elucidated as well. Furthermore, this review addresses the current tasks, and forthcoming directions are briefly summarized of PEM/AEMs for PEMFCs, DMFCs, AMFCs.

引用

页数：22

共 127 条

[21] Preparation and characterization of crosslinked anion exchange membrane (AEM) materials with poly(phenylene ether)-based short hydrophilic block for use in electrochemical applications [J].