Mirror symmetric Green-Color magnetic circularly polarized luminescence from TbIII-containing inorganics under North-up and South-up Faraday geometries

被引：5

作者：

Kimoto, Takahiro ^{[1
]}

Okuno, Mako ^{[1
]}

Nunotani, Naoyoshi ^{[2
]}

Imanaka, Nobuhito ^{[2
]}

Fujiki, Michiya ^{[3
]}

Imai, Yoshitane ^{[1
]}

机构：

[1] Kindai Univ, Fac Sci & Engn, Dept Appl Chem, 3-4-1 Kowakae, Higashiosaka, Osaka 5778502, Japan

[2] Osaka Univ, Fac Engn, Dept Appl Chem, 2-1 Yamadaoka, Suita, Osaka 5650871, Japan

[3] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300192, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2021年 / 134卷

基金：

日本学术振兴会;

关键词：

Chirality; Color diagram; Inorganic luminophore; Magnetic circularly polarized luminescence; Terbium; PHOTOLUMINESCENCE; COMPLEXES; STATES;

D O I：

10.1016/j.inoche.2021.109034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The present paper reports on three new achiral terbium(III) inorganics that emit strong green-color magnetic circularly polarized luminescence (MCPL) (|g(MCPL)| & LE; 5.4 x 10(-3) T-1 at 490-550 nm) when embedded in a KBr pellet in the presence of a 1.7 T external magnetic field. The signs of the green MCPL spectra are controllable by altering the S-up and N-up directions of the external magnetic field. Divalent manganese(II) and trivalent terbium(III) emit similar green luminescence; however, their wavelengths and MCPL characteristics are very different. Hence, we anticipate that these green-color MCPL substances can be used as new security pigments.

引用

页数：4

共 27 条

[1] Synthesis and photoluminescence properties of Ba2CaZn2Si6O17:Tb3+ green phosphor [J].

Annadurai, G. ;

Jayachandiran, M. ;

Kennedy, S. Masilla Moses ;

Sivakumar, V. .

MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2016, 208 :47-52

[2] Assembly of the Thiolated [Au1Ag22(S-Adm)12]3+ Superatom Complex into a Framework Material through Direct Linkage by SbF6- Anions [J].

Chen, Shuang ;

Du, Wenjun ;

Qin, Chenwanli ;

Liu, Danyu ;

Tang, Li ;

Liu, Ying ;

Wang, Shuxin ;

Zhu, Manzhou .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (19) :7542-7547

[3] Achieving high circularly polarized luminescence with push-pull helicenic systems: from rationalized design to top-emission CP-OLED applications [J].

Dhbaibi, Kais ;

Abella, Laura ;

Meunier-Della-Gatta, Sylvia ;

Roisnel, Thierry ;

Vanthuyne, Nicolas ;

Jamoussi, Bassem ;

Pieters, Gregory ;

Racine, Benoit ;

Quesnel, Etienne ;

Autschbach, Jochen ;

Crassous, Jeanne ;

Favereau, Ludovic .

CHEMICAL SCIENCE, 2021, 12 (15) :5522-5533

[4] Characterization of tetrakis(thiadiazole)porphyrazine metal complexes by magnetic circular dichroism and magnetic circularly polarized luminescence [J].

Ghidinelli, Simone ;

Abbate, Sergio ;

Mazzeo, Giuseppe ;

Paoloni, Lorenzo ;

Viola, Elisa ;

Ercolani, Claudio ;

Donzello, Maria Pia ;

Longhi, Giovanna .

CHIRALITY, 2020, 32 (06) :808-816

[5] Generation of Circularly Polarized Luminescence by Symmetry Breaking [J].

Imai, Yoshitane .

SYMMETRY-BASEL, 2020, 12 (11) :1-13

[6] Magnetic Circular Polarization of Exciton Photoluminescence [J].

Ivchenko, E. L. .

PHYSICS OF THE SOLID STATE, 2018, 60 (08) :1514-1526

[7] Enhancement in Photoluminescence of Gd2O2CO3:Tb3+ Submicron Particles by Introducing Yttrium into the Oxycarbonate Lattice [J].

Kim, Sun Woog ;

Masui, Toshiyuki ;

Matsushita, Hitoshi ;

Imanaka, Nobuhito .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (05) :J181-J185

[8] Ambidextrous Solid-state Magnetic Circularly Polarized Luminescence (MCPL) from Red-Green-Blue Inorganic Luminophores without Molecular Chirality [J].

Kimoto, Takahiro ;

Mimura, Yuki ;

Fujiki, Michiya ;

Imai, Yoshitane .

CHEMISTRY LETTERS, 2021, 50 (05) :916-919

[9] Singlet-Triplet Splittings in the Luminescent Excited States of Colloidal Cu+:CdSe, Cu+:InP, and CuInS2 Nanocrystals: Charge-Transfer Configurations and Self-Trapped Excitons [J].

Knowles, Kathryn E. ;

Nelson, Heidi D. ;

Kilburn, Troy B. ;

Gamelin, Daniel R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (40) :13138-13147

[10] Synthesis and luminescence properties of Tb3+:NaGd(WO4)2 novel green phosphors [J].

Liao, Jinsheng ;

Qiu, Bao ;

Lai, Huasheng .

JOURNAL OF LUMINESCENCE, 2009, 129 (07) :668-671

← 1 2 3 →