A novel dual-graphite aluminum-ion battery

被引：104
作者：
Wang, Shuai [1 ]
Jiao, Shuqiang [1 ,4 ]
Song, Wei-Li [2 ]
Chen, Hao-Sen [2 ]
Tu, Jiguo [1 ]
Tian, Donghua [1 ]
Jiao, Handong [1 ]
Fu, Chaopeng [3 ]
Fang, Dai-Ning [2 ]
机构：
[1] Univ Sci & Technol Beijing, State Key Lab Adv Met, Beijing 100083, Peoples R China
[2] Beijing Inst Technol, Inst Adv Struct Technol, Beijing 100081, Peoples R China
[3] Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, Shanghai 200240, Peoples R China
[4] Univ Sci & Technol Beijing, Beijing Key Lab Magnetophotoelect Composite & Int, Beijing 100083, Peoples R China
来源：
ENERGY STORAGE MATERIALS | 2018年 / 12卷
基金：
中国国家自然科学基金;
关键词：
Dual-graphite; Aluminum-ion battery; High discharge voltage; Ionic liquid electrolyte; ELECTRICAL ENERGY-STORAGE; HIGH-VOLTAGE; ELECTROCHEMICAL INTERCALATION; ANODE MATERIAL; GRAPHENE; CATHODE; ELECTRODES;
D O I：
10.1016/j.ensm.2017.12.010
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Advanced rechargeable batteries with long cycle life, high safety and low cost through multiple electrochemically reversible reactions are practically attractive. Recently, aluminum-ion batteries have attracted extraordinary attention owing to their unique advantages, such as low cost, low flammability and high stability. Herein, we firstly introduce a reversible dual-graphite intercalation chemistry with simultaneous deposition of Al3+ and intercalation of AlCl4- in graphitic materials for a new aluminum-ion battery based on an ionic liquid electrolyte. This novel dual-graphite aluminum-ion battery (DGAB) shows excellent cycling life with a stable discharge capacity of similar to 70 mA h g(-1) at 20 mA g(-1), a superior cycling coulombic efficiency (98.5%) and great rate capability, retaining similar to 70 mA h g(-1) over 600 continuous cycles. In addition, the battery offers a high discharge voltage approaching 2.1 V (vs. Al3+/Al). This work paves ways for further developing aluminum-ion batteries for the wide range of energy storage applications.
引用
收藏
页码：119 / 127
页数：9
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