Microwave-assisted synthesis and characterization of new soluble metal-free and metallophthalocyanines substituted with four tetrathiamacrocycles through oxy bridges

被引：37

作者：

Biyikhoglu, Zekeriya ^{[1
]}

Acar, Irfan ^{[1
]}

Kantekin, Halit ^{[1
]}

机构：

[1] Karadeniz Tech Univ, Fac Arts & Sci, Dept Chem, TR-61080 Trabzon, Turkey

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 06期

关键词：

tetrathiamacrocycles; metallophthalocyanine; synthesis; microwave; phthalonitrile;

D O I：

10.1016/j.inoche.2008.02.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new soluble metal-free and Ni(II), Zn(II), Co(II), Cu(II), Pb(II) phthalocyanines with four, tetrathiamacrocycles were obtained from 4-[(11-hyroxy-1,5,9,13-tetrathiacyclohexadecan-3-yl)oxy]phthalonitrile 3 and the corresponding divalent metal salt (NiCl(2), Zn(CH(3)COO)(2), CoCl(2), CuCl(2) and PbO). Metal-free and metallophthalocyanines showed the enhanced solubility in organic solvents. The structures of the target compounds were confirmed using elemental analysis, IR, (1)H NMR, (13)C NMR, UV-vis and MS spectral data. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：630 / 632

页数：3

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