Electron paramagnetic resonance (EPR) study of the impurity Gd3+ ions in the multi-site SrY2O4 crystal iso-structural to the magnetically-frustrated SrGd2O4 compound is reported. Analysis of the angular dependences of the EPR spectra at room temperature allowed us to establish the spin-level energy patterns in the ground states of the Gd3+ ions at the Y(1) and Y(2) sites. Parameters of the spin-Hamiltonian in the frames related to the crystal axes and to the principal center axes are determined.
机构:
Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China
Chengdu Univ Informat & Technol, Dept Opt & Elect, Chengdu 610225, Peoples R ChinaSichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China
Wei-Qing, Yang
Wen-Chen, Zheng
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机构:
Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China
Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R ChinaSichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China
机构:
Rutgers State Univ, Dept Chem, Newark, NJ 07102 USARutgers State Univ, Dept Chem, Newark, NJ 07102 USA
Acikgoz, Muhammed
Rudowicz, Czeslaw
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Adam Mickiewicz Univ, Fac Chem, PL-61614 Poznan, Poland
West Pomeranian Univ Technol, Inst Phys, Szczecin, PolandRutgers State Univ, Dept Chem, Newark, NJ 07102 USA