Spin-Hamiltonian parameters and zero-field splitting of impurity Gd3+ ions in SrY2O4 crystal

被引:6
作者
Gabbasov, B. F. [1 ]
Zverev, D. G. [1 ]
Gilmutdinov, I. F. [1 ]
Batulin, R. G. [1 ]
Kiiamov, A. G. [1 ]
Nikitin, S., I [1 ]
Yusupov, R., V [1 ]
机构
[1] Kazan Fed Univ, Kremlevskaya Str 18, Kazan 420008, Russia
关键词
Strontium yttrate; Gadolinium impurity; Electron paramagnetic resonance; Zero-field splitting; Spin-Hamiltonian parameters; SYMMETRY;
D O I
10.1016/j.jmmm.2018.09.044
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Electron paramagnetic resonance (EPR) study of the impurity Gd3+ ions in the multi-site SrY2O4 crystal iso-structural to the magnetically-frustrated SrGd2O4 compound is reported. Analysis of the angular dependences of the EPR spectra at room temperature allowed us to establish the spin-level energy patterns in the ground states of the Gd3+ ions at the Y(1) and Y(2) sites. Parameters of the spin-Hamiltonian in the frames related to the crystal axes and to the principal center axes are determined.
引用
收藏
页码:638 / 642
页数:5
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