Synthesis of Inherently Chiral Azacalix[4]arenes and Diazadioxacalix[4]arenes

被引：43

作者：

Katz, Jeffrey L. ^{[1
]}

Tschaen, Brittany A. ^{[1
]}

机构：

[1] Colby Coll, Dept Chem, Waterville, ME 04901 USA

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 19期

基金：

美国国家科学基金会;

关键词：

CRYSTAL-STRUCTURE; CAVITY; OXACALIXARENES; COMPLEXATION;

D O I：

10.1021/ol1017454

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Described are nucleophilic aromatic substitution reactions for the synthesis of inherently chiral azacalix[4]arenes and diazadioxacalix[4]arenes comprised of two or three different aromatic monomers. A variety of functional groups are tolerated at the 2-, 4-, and 5-positions on the nucleophilic-component monomers; reactions are run under ambient atmosphere; and the macrocycles are constructed without isolation of intermediate linear species.

引用

页码：4300 / 4303

页数：4

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