A Novel Hydrogen-Bonded 3D Network with Unusual Coordination Mode

被引：6

作者：

Wang, Fang-Kuo ^{[1
,2
]}

Yang, Shi-Yao ^{[1
]}

Huang, Rong-Bing ^{[1
]}

Zheng, Lan-Sun ^{[1
]}

机构：

[1] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China

[2] W Anhui Univ, Dept Chem, Luan 237012, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2010年 / 40卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Hydrogen-bond; 3D network; Crystal structure; Photoluminescence; METAL-ORGANIC FRAMEWORKS; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURES; ACID; ZINC; COMPLEXES; POLYMERS; DESIGN; ARCHITECTURES; SYSTEM;

D O I：

10.1007/s10870-010-9750-6

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A hydrogen-bonded 3D network [Mn(H2O)(2) (nbdc)](n), 1 H(2)nbdc = 2-aminoterephthalic acid) crystallizes in the monoclinic, space group P2(1)/c, a = 9.6418(6), b = 6.4491(4), c = 15.3216(9) angstrom, beta = 95.792(1)degrees, Z = 4 and displays unusual coordination mode (Mn-N (from nbdc), 2.275(3) angstrom). In the structure of 1, the Mn2+ ions are connected with mu(2)-carboxylates to form left handed and right handed chiral helix chains (-Mn-O-C-O-)(n), which are connected by nbdc ligands to form 2D sheet along b axis, then these 2D sheets are further linked together through Mn-OH2 center dot center dot center dot O (from mu(2) carboxylate) -Mn hydrogen-bonds to construct the 3D network.

引用

页码：837 / 840

页数：4

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