A RhNiP/rGO hybrid for efficient catalytic hydrogen generation from an alkaline solution of hydrazine

被引：35

作者：

Du, Xiaoqiong ^{[1
]}

Tan, Shiyi ^{[1
]}

Cai, Ping ^{[1
]}

Luo, Wei ^{[1
]}

Cheng, Gongzhen ^{[1
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2016年 / 4卷 / 38期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORKS; DOPED POROUS CARBON; EVOLUTION REACTION; ROOM-TEMPERATURE; FORMIC-ACID; METHANOL ELECTROOXIDATION; PHOSPHIDE NANOPARTICLES; RHNI NANOPARTICLES; OXIDATION REACTION; DURABLE CATALYSTS;

D O I：

10.1039/c6ta05917a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Transition metal phosphide based hybrids (RhNiP/rGO) with different phosphorus contents have been successfully synthesized via a facile one-pot co-reduction route. Thanks to the synergistic electronic effect between Rh, Ni, and P, the as-synthesized RhNiP/rGO hybrid exhibits superior catalytic activity toward hydrogen generation from an alkaline solution of hydrazine.

引用

页码：14572 / 14576

页数：5

共 49 条

[11] New approaches to hydrogen storage [J].

Graetz, Jason .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) :73-82

[12] Liquid-Phase Chemical Hydrogen Storage: Catalytic Hydrogen Generation under Ambient Conditions [J].

Jiang, Hai-Long ;

Singh, Sanjay Kumar ;

Yan, Jun-Min ;

Zhang, Xin-Bo ;

Xu, Qiang .

CHEMSUSCHEM, 2010, 3 (05) :541-549

[13] A Class of (Pd-Ni-P) Electrocatalysts for the Ethanol Oxidation Reaction in Alkaline Media [J].

Jiang, Rongzhong ;

Tran, Dat T. ;

McClure, Joshua P. ;

Chu, Deryn .

ACS CATALYSIS, 2014, 4 (08) :2577-2586

[14]

Koper MTM, 2013, NAT CHEM, V5, P255, DOI 10.1038/nchem.1600

[15] RETRACTED: Synthesis of octahedral, truncated octahedral, and cubic Rh2Ni nanocrystals and their structure-activity relationship for the decomposition of hydrazine in aqueous solution to hydrogen (Publication with Expression of Concern. See vol. 10, pg. 13289, 2018) (Retracted article. See vol. 11, pg. 16689, 2019) [J].

Li, Chun ;

Wang, Tao ;

Chu, Wei ;

Wu, Ping ;

Tong, Dong Ge .

NANOSCALE, 2016, 8 (13) :7043-7055

[16] Facile synthesis of various highly dispersive CoP nanocrystal embedded carbon matrices as efficient electrocatalysts for the hydrogen evolution reaction [J].

Li, Mian ;

Liu, Xiaotian ;

Xiong, Yueping ;

Bo, Xiangjie ;

Zhang, Yufan ;

Han, Ce ;

Guo, Liping .

JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (08) :4255-4265

[17] A Single-Component Liquid-Phase Hydrogen Storage Material [J].

Luo, Wei ;

Campbell, Patrick G. ;

Zakharov, Lev N. ;

Liu, Shih-Yuan .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (48) :19326-19329

[18] The hierarchical nanowires array of iron phosphide integrated on a carbon fiber paper as an effective electrocatalyst for hydrogen generation [J].

Lv, Cuncai ;

Peng, Zhen ;

Zhao, Yaoxing ;

Huang, Zhipeng ;

Zhang, Chi .

JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (04) :1454-1460

[19] Evolution of nanoscale amorphous, crystalline and phase-segregated PtNiP nanoparticles and their electrocatalytic effect on methanol oxidation reaction [J].

Ma, Yanjiao ;

Wang, Rongfang ;

Wang, Hui ;

Linkov, Vladimir ;

Ji, Shan .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (08) :3593-3602

[20] Amorphous Molybdenum Phosphide Nanoparticles for Electrocatalytic Hydrogen Evolution [J].

McEnaney, Joshua M. ;

Crompton, J. Chance ;

Callejas, Juan F. ;

Popczun, Eric J. ;

Biacchi, Adam J. ;

Lewis, Nathan S. ;

Schaak, Raymond E. .

CHEMISTRY OF MATERIALS, 2014, 26 (16) :4826-4831

← 1 2 3 4 5 →