[{TcI(NO)(LOMe)(PPh3)Cl}2Ag](PF6) and [TcII(NO)(LOMe)(PPh3)Cl](PF6): Two Unusual Technetium Complexes with a "Klaui-type" Ligand

被引：5

作者：

Jungfer, Maximilian Roca ^{[1
]}

Ernst, Moritz Johannes ^{[1
]}

Hagenbach, Adelheid ^{[1
]}

Abram, Ulrich ^{[1
]}

机构：

[1] Free Univ Berlin, Inst Chem & Biochem, Fabeckstr 34-36, D-14195 Berlin, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2022年 / 648卷 / 04期

关键词：

Technetium; nitrosyl complexes; EPR; tripod ligands; ORGANOMETALLIC CHEMISTRY; TC-99M; COORDINATION; HYDROLYSIS; REACTIVITY; MECHANISM; AGENT;

D O I：

10.1002/zaac.202100316

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Tc-I(NO)(L-OMe)(PPh3)Cl] ({L-OMe}(-) = eta(5)-cyclopentadienyltris(dimethyl phosphito-P)cobaltate(III)) with Ag(PF6) gives two unexpected products: the dimeric technetium(I) complex [{Tc(NO)(L-OMe)(PPh3)Cl}(2)Ag](PF6) with a central Ag+ ion and the cationic Tc(II) compound [Tc(NO)(L-OMe)(PPh3)Cl](PF6). The products have been studied spectroscopically and by X-ray diffraction.

引用

页数：6

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