Synthesis of a novel β-cyclodextrin derivative with high solubility and the electrochemical properties of ferrocene-carbonyl-β-cyclodextrin inclusion complex as an electron transfer mediator

被引：23

作者：

Zheng, Longzhen ^{[1
]}

Xiong, Leyan ^{[1
]}

Junhua, L. ^{[1
]}

Xinjia, L. ^{[1
]}

Sun, Juan ^{[1
]}

Yang, Shaoming ^{[1
]}

Xia, Jian ^{[1
]}

机构：

[1] E China Jiao Tong Univ, Dept Chem & Chem Engn, Jiangsu 330013, Peoples R China

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2008年 / 10卷 / 02期

基金：

中国国家自然科学基金;

关键词：

carbonyl-beta-cyclodextrin; high solubility; ferrocene; inclusion complex; bioelectrocatalysis;

D O I：

10.1016/j.elecom.2007.12.015

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A facile strategy for preparing water-soluble beta-cyclodextrin derivative, carbonyl-beta-cyclodextrin, was developed by partial oxidation of beta-cyclodextrin. The solubility of carbonyl-beta-cyclodextrin was greatly enhanced due to the breaking of intramolecular hydrogen bond network of beta-cyclodextrin. Ferrocene was included into the cavity of carbonyl-beta-cyclodextrin to form Fc-carbonyl-beta-cyclodextrin inclusion complex. The electrochemical properties of Fc-carbonyl-beta-cyclodextrin were studied. The Fc-carbonyl-beta-cyclodextrin complex exhibited high solubility and was shown to be good electrochemical probe and efficient mediator for bioelectrocatalysis of glucose oxidase. The bioelectrocatalytic efficacy of Fc-carbonyl-beta-cyclodextrin complex opened up homogeneous applications of ferrocene in amperometric biosensor systems. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：340 / 345

页数：6

共 23 条

[1] Aleksandrovskii Y. A., 1981, BIOKHIMIYA, V46, P708
[2] BARTLETT P N, 1991, Progress in Reaction Kinetics, V16, P55
[3] BROWN RS, 1991, ELECTROANAL, V3, P443
[4] FERROCENE-MEDIATED ENZYME ELECTRODE FOR AMPEROMETRIC DETERMINATION OF GLUCOSE
CASS, AEG
DAVIS, G
FRANCIS, GD
HILL, HAO
ASTON, WJ
HIGGINS, IJ
PLOTKIN, EV
SCOTT, LDL
TURNER, APF
[J]. ANALYTICAL CHEMISTRY, 1984, 56 (04) : 667 - 671
[5] Mediated biosensors
Chaubey, A
Malhotra, BD
[J]. BIOSENSORS & BIOELECTRONICS, 2002, 17 (6-7) : 441 - 456
[6] Electrochemical studies of ferrocene derivatives and their complexation by β-cyclodextrin
Coutouli-Argyropoulou, E
Kelaidopoulou, A
Sideris, C
Kokkinidis, G
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 477 (02) : 130 - 139
[7] THE ELECTROCHEMISTRY OF HEXACYANORUTHENATE AT CARBON ELECTRODES AND THE USE OF RUTHENIUM COMPOUNDS AS MEDIATORS IN THE GLUCOSE GLUCOSE-OXIDASE SYSTEM
CRUMBLISS, AL
HILL, HAO
PAGE, DJ
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 206 (1-2): : 327 - 331
[8] ELECTROCHEMICAL TECHNIQUES FOR THE DEVELOPMENT OF AMPEROMETRIC BIOSENSORS
DAVIS, G
[J]. BIOSENSORS, 1985, 1 (02) : 161 - 178
[9] ENZYME ENTRAPMENT IN ELECTRICALLY CONDUCTING POLYMERS - IMMOBILIZATION OF GLUCOSE-OXIDASE IN POLYPYRROLE AND ITS APPLICATION IN AMPEROMETRIC GLUCOSE SENSORS
FOULDS, NC
LOWE, CR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 : 1259 - 1264
[10] ELECTRICAL COMMUNICATION BETWEEN A WATER-SOLUBLE 1,1'-DIMETHYLFERROCENE-2-HYDROXYPROPYL-BETA-CYCLODEXTRIN COMPLEX AND GLUCOSE-OXIDASE - BIOSENSOR APPLICATIONS
GROOM, CA
LUONG, JHT
[J]. BIOSENSORS & BIOELECTRONICS, 1994, 9 (4-5) : 305 - 313

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