The first porous MOF with photoswitchable linker molecules

被引：164

作者：

Modrow, Antje ^{[1
]}

Zargarani, Dordaneh ^{[2
]}

Herges, Rainer ^{[2
]}

Stock, Norbert ^{[1
]}

机构：

[1] Univ Kiel, Inst Anorgan Chem, D-24118 Kiel, Germany

[2] Univ Kiel, Otto Diels Inst Organ Chem, D-24098 Kiel, Germany

来源：

DALTON TRANSACTIONS | 2011年 / 40卷 / 16期

关键词：

METAL-ORGANIC FRAMEWORK; STORAGE;

D O I：

10.1039/c0dt01629b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We synthesized a porous twofold interpenetrated MOF [Zn-2(NDC)(2)(1)] (coined CAU-5) using 3-azo-phenyl-4,4'-bipyridine (1), 2,6-naphthalenedicarboxylic acid, and Zn(NO3)(2)center dot 6H(2)O. The azo-functionality protrudes into the pores, and can be switched, by irradiation with UV light (365 nm), from the thermodynamically stable trans-isomer to the cis-isomer. Back-switching was achieved thermally and with an irradiation wavelength of lambda(max) = 440 nm.

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收藏

页码：4217 / 4222

页数：6

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