Packing motifs in porphyrazine macrocycles carrying peripherally annulated thiadiazole rings: Crystal growths of metal-free and cobalt tetrakis(1,2,5-thiadiazole)porphyrazines

被引：26

作者：

Fujimori, M ^{[1
]}

Suzuki, Y ^{[1
]}

Yoshikawa, H ^{[1
]}

Awaga, K ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 47期

关键词：

crystal growth; magnetic properties; porphyrazines; structure elucidation; sulfur heterocycles;

D O I：

10.1002/anie.200352571

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The importance of the thiadiazole ring: While electrostatic interactions between the thiadiazole rings is responsible for the 2D close packing in the solid-state structure of tetrakis(thiadiazole) porphyrazine (TTDPzH 2, see X-ray crystal structure), the formation of a coordination bond between the ring and the cobalt ion results in the cobalt derivative TTDPzCo having a chain structure.

引用

页码：5863 / 5865

页数：3

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