Molecular electrocatalysis at soft interfaces

被引：87

作者：

Mendez, Manuel A. ^{[1
]}

Partovi-Nia, Raheleh ^{[1
]}

Hatay, Imren ^{[1
]}

Su, Bin ^{[1
]}

Ge, PeiYu ^{[1
]}

Olaya, Astrid ^{[1
]}

Younan, Nathalie ^{[1
]}

Hojeij, Mohamad ^{[1
]}

Girault, Hubert H. ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Lab Electrochim Phy & Analyt, CH-1015 Lausanne, Switzerland

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2010年 / 12卷 / 46期

关键词：

BAR-LIQUID INTERFACES; PHOTOINDUCED ELECTRON-TRANSFER; IONIC PARTITION DIAGRAMS; LIQUID/LIQUID INTERFACES; GRAPHITE-ELECTRODES; REDOX REACTIONS; THIN-LAYERS; HYDROGEN EVOLUTION; COBALT PORPHYRINS; OXYGEN REDUCTION;

D O I：

10.1039/c0cp00590h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The fundamental aspects of electrochemistry at liquid-liquid interfaces are introduced to present the concept of molecular electrocatalysis. Here, a molecular catalyst is adsorbed at the interface to promote a proton coupled electron transfer reaction such as hydrogen evolution or oxygen reduction using lipophilic electron donors.

引用

页码：15163 / 15171

页数：9

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