Sub-picosecond IR study of the reactive intermediate in an alkane C-H bond activation reaction by CpRh(CO)2

被引:45
作者
Asbury, JB
Ghosh, HN
Yeston, JS
Bergman, RG
Lian, TQ
机构
[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[3] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA 94720 USA
关键词
D O I
10.1021/om980194f
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reactive intermediate in a cyclohexane C-H bond activation reaction by CpRh(CO)(2) has been identified as the cyclohexane solvate eta(5)-CPRh(CO)(C6H12) by sub-picosecond infrared spectroscopy.
引用
收藏
页码:3417 / 3419
页数:3
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