An expeditious solvent-free route to ionic liquids using microwaves

被引：256

作者：

Varma, RS ^{[1
]}

Namboodiri, VV ^{[1
]}

机构：

[1] US EPA, Clean Proc Branch, Natl Risk Management Res Lab, Cincinnati, OH 45268 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 07期

关键词：

D O I：

10.1039/b101375k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A microwave-assisted preparation of a series of ambient temperature ionic liquids, 1-alkyl-3-methylimidazolium (AMIM) halides, that proceeds via efficient reaction of 1-methylimidazole with alkyl halides/terminal dihalides under solvent-free conditions, is described.

引用

页码：643 / 644

页数：2

共 17 条

[1] Copper(I) mediated living radical polymerisation in an ionic liquid [J].

Carmichael, AJ ;

Haddleton, DM ;

Bon, SAF ;

Seddon, KR .

CHEMICAL COMMUNICATIONS, 2000, (14) :1237-1238

[2] Solvent extraction of strontium nitrate by a crown ether using room-temperature ionic liquids [J].

Dai, S ;

Ju, YH ;

Barnes, CE .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (08) :1201-1202

[3] Eyes on ionic liquids [J].

Freemantle, M .

CHEMICAL & ENGINEERING NEWS, 2000, 78 (20) :37-+

[4] New horizons for ionic liquids -: Green 'designer solvents' find additional effective uses, now for enzyme catalysis and in classic organic synthesis [J].

Freemantle, M .

CHEMICAL & ENGINEERING NEWS, 2001, 79 (01) :21-25

[5]

Holbrey JD., 1999, CLEAN PRODUCTS PROCE, V1, P223, DOI [10.1007/s100980050036, DOI 10.1007/S100980050036]

[6] Room temperature ionic liquids as novel media for 'clean' liquid-liquid extraction [J].

Huddleston, JG ;

Willauer, HD ;

Swatloski, RP ;

Visser, AE ;

Rogers, RD .

CHEMICAL COMMUNICATIONS, 1998, (16) :1765-1766

[7] Polycations. Part X. LIPs, a new category of room temperature ionic liquid based on polyammonium salts [J].

Lall, SI ;

Mancheno, D ;

Castro, S ;

Behaj, V ;

Cohen, JLI ;

Engel, R .

CHEMICAL COMMUNICATIONS, 2000, (24) :2413-2414

[8] Solvent-free organic syntheses - using supported reagents and microwave irradiation [J].

Varma, RS .

GREEN CHEMISTRY, 1999, 1 (01) :43-55

[9] Solvent-free synthesis of heterocyclic compounds using microwaves [J].

Varma, RS .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1999, 36 (06) :1565-1571

[10]

VARMA RS, 2000, GREEN CHEM CHALLENGI, P221

← 1 2 →