Hydrothermal syntheses, structures and characterizations of three one-dimensional polyoxomolybdates with 4,4′-dimethylenebiphenyl diphosphonic acid as bridge

被引：9

作者：

Zhang, HS ^{[1
]}

Fu, RB ^{[1
]}

Zhang, HJ ^{[1
]}

Wu, XT ^{[1
]}

Li, YM ^{[1
]}

Wang, LS ^{[1
]}

Huang, XH ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2005年 / 178卷 / 05期

基金：

中国国家自然科学基金;

关键词：

hydrothermal synthesis; crystal structure; metal-organic subunit; one-dimensional; polyoxomolybdate; 4,4 '-dirnethylenebiphenyldiphosphonic acid;

D O I：

10.1016/j.jssc.2005.02.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three heterometallic 1-D polymers, [{Ni(1,10-phen)(2)(H2O)}(2) {(Mo5O15)(4,4'-dbp)} (.) (5.75H(2)O)] (4,4-dbp = O3PCH2C6H4C6 H4CH2PO3) (1), [{Co(1,10-phen)(2)(H2O)}(2) {(Mo5O15)(4,4'-dbp)} (.) (5.5H(2)O)] (2) and [{Ni(2,2'-bpy)(3)} {Ni(2,2'-bpy)(2)(H2O)} {(Mo5O15)(4,4'-dbp)} (.) (4.75H(2)O)] (3), have been synthesized under hydrothermal conditions. Their structures were determined by single crystal X-ray diffraction. The 1-D chains is constructed of [Mo5O15(4,4'-dbp)](4-) units, which are further decorated and charge compensated by [M(1,10-phen)(2)] (M = Ni, Co) or [Ni(2,2'-bpy)(2)] subunits. The thermogravimetric analyses and magnetic properties of 1 and 2 were studied. (c) 2005 Elsevier Inc. All rights reserved.

引用

页码：1349 / 1355

页数：7

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