Intramolecular photoredox reactions of 1,2-naphthoquinone derivatives

被引：9

作者：

Ando, Yoshio ^{[1
]}

Wakita, Fumihiro ^{[1
]}

Ohmori, Ken ^{[1
]}

Suzuki, Keisuke ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528551, Japan

来源：

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS | 2018年 / 28卷 / 16期

关键词：

Photoreaction; Redox reaction; 1,2-Naphthoquinone; C-H functionalization;

D O I：

10.1016/j.bmcl.2018.05.056

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

Photoirraditation of substituted 1,2-naphthoquinones gives the corresponding oxacycle via intramolecular redox reaction, which enabled net C-H functionalization of the proximal position to the excited carbonyl group of the quinones. The substrate scope and mechanistic insights are described.

引用

收藏

页码：2663 / 2666

页数：4

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