Two-photon resonant hyperpolarizability of an H-shaped molecule studied by wavelength-tunable hyper-Rayleigh scattering

被引：9

作者：

Zhu, Jing ^{[1
]}

Lu, Changgui ^{[1
]}

Cui, Yiping ^{[1
]}

Zhang, Chaozhi ^{[2
]}

Lu, Guoyuan ^{[2
]}

机构：

[1] Southeast Univ, Adv Photon Ctr, Nanjing 210096, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Dept Chem, Nanjing 210093, Peoples R China

来源：

JOURNAL OF CHEMICAL PHYSICS | 2010年 / 133卷 / 24期

关键词：

NONLINEAR-OPTICAL PROPERTIES; HIGH-FREQUENCY DEMODULATION; CHARGE-TRANSFER CHROMOPHORE; RAMAN EXCITATION PROFILES; 1ST HYPERPOLARIZABILITY; LIGHT-SCATTERING; MULTIPHOTON FLUORESCENCE; CORRELATED CHROMOPHORES; PARA-NITROANILINE; ONE-PHOTON;

D O I：

10.1063/1.3506421

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Wavelength dependent hyper-Rayleigh scattering measurements have been performed by using a fluorescence spectrometer. With this detection strategy, first molecular hyperpolarizability (beta) of a dual charge-transfer (H-shaped) chromophore and its monomer have been measured in two-photon resonance range from 670 to 950 nm as well as at off-resonance of 1064 nm. The absorption and resonance hyper-Rayleigh profiles can be simulated reasonably well with a common set of parameters. In addition, both resonance and off-resonance results show that beta(0) per chromophore has a remarkable enhancement for the H-shaped molecule as large as 1.7, compared with that of the monomer, which could be ascribed to two physical effects: (1) coherent enhancement of two chromophores and (2) intramolecular dipole-dipole interaction, which was confirmed by their fluorescence-decay behaviors. (C) 2010 American Institute of Physics. [doi:10.1063/1.3506421]

引用

页数：7

共 55 条

[1] Electric field induced second harmonic generation:: Second and third-order hyperpolarizabilities of 4-amino-4′-nitrodiphenyl sulfoxide [J].

Abdel-Halim, HM .

JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (01) :484-487

[2] Large enhancement of electronic first hyperpolarizability in Donor1-π-Donor2 chromophores with charge defects [J].

Acebal, P ;

Blaya, S ;

Carretero, L .

CHEMICAL PHYSICS LETTERS, 2004, 394 (1-3) :76-79

[3] Dispersion of nonlinear refraction and two-photon absorption using a white-light continuum Z-scan [J].

Balu, M ;

Hales, J ;

Hagan, DJ ;

Van Stryland, EW .

OPTICS EXPRESS, 2005, 13 (10) :3594-3599

[4] DOUBLE-QUANTUM LIGHT SCATTERING BY MOLECULES [J].

BERSOHN, R ;

PAO, YH ;

FRISCH, HL .

JOURNAL OF CHEMICAL PHYSICS, 1966, 45 (09) :3184-&

[5] Quasi-phase-matching in chiral materials [J].

Busson, B ;

Kauranen, M ;

Nuckolls, C ;

Katz, TJ ;

Persoons, A .

PHYSICAL REVIEW LETTERS, 2000, 84 (01) :79-82

[6] Accurate determination and modeling of the dispersion of the first hyperpolarizability of an efficient zwitterionic nonlinear optical chromophore by tunable wavelength hyper-Rayleigh scattering [J].

Campo, Jochen ;

Wenseleers, Wim ;

Goovaerts, Etienne ;

Szablewski, Marek ;

Cross, Graham H. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (01) :287-296

[7] Highly sensitive setup for tunable wavelength hyper-Rayleigh scattering with parallel detection and calibration data for various solvents [J].

Campo, Jochen ;

Desmet, Filip ;

Wenseleers, Wim ;

Goovaerts, Etienne .

OPTICS EXPRESS, 2009, 17 (06) :4587-4604

[8]

Chemia D.S., 1987, NONLINEAR OPTICAL PR

[9]

Clays K, 1998, ADV MATER, V10, P643, DOI 10.1002/(SICI)1521-4095(199806)10:9<643::AID-ADMA643>3.0.CO

[10]

2-L

← 1 2 3 4 5 6 →