Versatile polyiodopyrazoles: synthesis and biocidal promise

被引：24

作者：

Chand, Deepak ^{[1
]}

Shreeve, Jean'ne M. ^{[1
]}

机构：

[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 16期

关键词：

CONVENIENT SYNTHESIS;

D O I：

10.1039/c4cc09775k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient route to polyiodopyrazoles, 3,4,5-triiodopyrazole (1), 1-methyl-3,4,5-triiodopyrazole (2) and 1-diiodomethyl-3,4,5-triiodo-pyrazole (3), opens the door to prospective biocides. Nitration of 1 and 2 gives the previously inaccessible compounds, 3,4-dinitro-5-iodopyrazole (4), and 3,4-dinitro-5-iodo-1-methylpyrazole (5), respectively. These synthetic pathways will open many fronts for pyrazole chemistry.

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收藏

页码：3438 / 3441

页数：4

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