Base-Catalyzed Transcarbamoylation

被引：8
|
作者：
Rhone, Benoit [1 ,2 ,3 ]
Semetey, Vincent [1 ,2 ]
机构：
[1] PSL Res Univ, Inst Rech Chim Paris, CNRS, Chim ParisTech, 11 Rue Pierre & Marie Curie, F-75005 Paris, France
[2] PSL Res Univ, Inst Curie, Lab Phys Chim Curie, F-75005 Paris, France
[3] UPMC Univ Paris 06, Sorbonne Univ, F-75005 Paris, France
来源：
SYNLETT | 2017年 / 28卷 / 15期
关键词：
urethane; carbamate; transcarbamoylation; transurethanisation; base; SOLID-PHASE SYNTHESIS; TRANSESTERIFICATION; POLYURETHANES; EFFICIENT;
D O I：
10.1055/s-0036-1588866
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Inorganic bases such as NaH, KOt-Bu, NaOH, or KOH are efficient catalysts to promote the transcarbamoylation reaction between urethanes and a variety of primary and secondary alcohols under mild conditions. They constitute an alternative to organometallic catalysis and can be applied to aliphatic or aromatic urethanes.
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页码：2004 / 2007
页数：4
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