2-(4-Methoxyphenyl)-4H-1,3,2-benzoxathiaphosphinine 2-sulfide

被引：2

作者：

Osyanin, Vitaly A. ^{[2
]}

Ivleva, Elena A. ^{[2
]}

Rybakov, Victor B. ^{[1
]}

Klimochkin, Yurij N. ^{[2
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

[2] Samara State Tech Univ, Samara 443100, Russia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

基金：

俄罗斯基础研究基金会;

关键词：

LAWESSONS REAGENT;

D O I：

10.1107/S1600536810053146

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, C14H13O2PS2, contains two crystallographically independent molecules, which differ in the conformation of the 1,3,2-benzoxathiaphosphinine moieties (screw boat in the first molecule and envelope in the second molecule). In the crystal, neither classical nor non-classical hydrogen bonds are found. Weak interactions (about 2.9-3.0 angstrom) between the lone pair of the terminal S atoms with H atoms occur. This compound was further characterized by H-1 NMR and IR spectroscopy.

引用

页码：O388 / U843

页数：13

共 13 条

[1] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[2]

[Anonymous], 2010, CRYSALIS PRO

[3] THE ANALYTICAL CALCULATION OF ABSORPTION IN MULTIFACETED CRYSTALS [J].

CLARK, RC ;

REID, JS .

ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 :887-897

[4] GENERAL DEFINITION OF RING PUCKERING COORDINATES [J].

CREMER, D ;

POPLE, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1354-1358

[5] OLEX2: a complete structure solution, refinement and analysis program [J].

Dolomanov, Oleg V. ;

Bourhis, Luc J. ;

Gildea, Richard J. ;

Howard, Judith A. K. ;

Puschmann, Horst .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 :339-341

[6] Synthesis of new heterocyclic compounds using Lawesson reagent [J].

El-Kateb, AA ;

Abd El-Rahman, NM .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2006, 181 (02) :249-254

[7] REACTION OF 1-(DIPHENYLMETHYLENE)-2(1H)-NAPHTHALENONE AND 4-(DIPHENYLMETHYLENE)-1(4H)-NAPHTHALENONE WITH THIOL PHOSPHORIC-ACIDS, LAWESSON REAGENT AND PHOSPHORUS PENTASULFIDE [J].

ELKATEB, AA ;

HENNAWY, IT ;

SHABANA, R ;

ABDELMALEK, HA .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1991, 63 (1-2) :13-17

[8]

Farrugia L.J., 1997, J. Appl. Crystallogr., V30, P565, DOI [10.1107/S0021889897003117, DOI 10.1107/S0021889897003117]

[9] Synthesis of Phosphonodithioate, Oxathiaphosphinin, Oxathiaphosphole, and Dithiaphosphole Derivatives from the Reaction of Lawesson's Reagent with Phenolic Mannich Bases and Oxime Derivatives [J].

Maigali, Soher S. ;

Shabana, Rashad ;

El-Hussieny, Marwa ;

Soliman, Fouad M. .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2009, 184 (09) :2408-2426

[10] Use of Lawesson's reagent in organic syntheses [J].

Ozturk, Turan ;

Ertas, Erdal ;

Mert, Olcay .

CHEMICAL REVIEWS, 2007, 107 (11) :5210-5278

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