Synthesis and properties of new π-conjugated pyridine ligands with tetrathiafulvalene derivatives and the rhenium(I) tricarbonyl complexes

被引：17

作者：

Li, Gao-Nan ^{[1
]}

Wen, Di ^{[1
]}

Jin, Tao ^{[1
]}

Liao, Ya ^{[1
]}

Zuo, Jing-Lin ^{[1
]}

You, Xiao-Zeng ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China

来源：

TETRAHEDRON LETTERS | 2011年 / 52卷 / 06期

关键词：

Tetrathiafulvalene; Diels-Alder reaction; New pyridine ligands; Rhenium complexes; COORDINATION COMPLEX; CHARGE-TRANSFER; EMISSION;

D O I：

10.1016/j.tetlet.2010.11.129

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three new pi-conjugated pyridine ligands with redox-active tetrathiafulvalene (TTF) derivatives, L-1-L-3, have been synthesized and characterized. The Diels-Alder reaction is the key step for this multistep synthetic strategy. The crystal structures of L-1 and L-3 have been studied. The electrochemical and spectroscopic properties of these new ligands, as well as the corresponding tricarbonyl rhenium(I) complexes (ReL1(CO)(3)X, X = Cl, 5; X = Br, 6) have also been investigated. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：675 / 678

页数：4

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