Synthesis of chiral tripodal receptors under solvent-free conditions using microwave irradiation for investigation of anion and cation recognition properties

被引：0
|
作者：
Kaplan, Seref [1 ]
Ozturk, Gulsen [1 ]
Azizoglu, Sevil S. [1 ]
Togrul, Mahmut [1 ]
Turgut, Yilmaz [1 ]
机构：
[1] Dicle Univ, Fac Sci, Dept Chem, TR-21280 Diyarbakir, Turkey
来源：
ARKIVOC | 2018年
关键词：
Molecular recognition; tripodal receptors; cation and anion recognition; microwave; NMR titration; ASSISTED SYNTHESIS; BINDING; ACIDS; AMIDES;
D O I：
10.24820/ark.5550190.p010.759
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Amide based chiral tripodal receptor derivatives were synthesized under microwave irradiation in quite high yields (76%- 84%) and they were characterized by IR and 1D, 2D, H-1- and C-13-NMR spectroscopies. The recognition properties of these tripodal receptors towards some anions and organic ammonium salts were investigated by H-1-NMR titration in DMSO-d(6). The tripodal (S)-phenyl receptor demonstrated a highly significant enantiomeric selectivity towards the (S)-(-)-1-phenyletylammonium perchlorate (ERF= 91.74 S). [GRAPHICS] .
引用
收藏
页码：482 / 494
页数：13
相关论文
共 50 条
  • [31] Microwave synthesis of metal phthalocyanines under solvent-free conditions
    Jung, KS
    Kwon, JH
    Shon, SM
    Ko, JP
    Shin, JS
    Park, SS
    JOURNAL OF MATERIALS SCIENCE, 2004, 39 (02) : 723 - 726
  • [32] Microwave synthesis of metal phthalocyanines under solvent-free conditions
    Ki Suck Jung
    Jong Ho Kwon
    Se Mo Shon
    Jin Phil Ko
    Jun Sik Shin
    Seong Soo Park
    Journal of Materials Science, 2004, 39 : 723 - 726
  • [33] Microwave irradiation synthesis of 2-substituted benzimidazoles using PPA as a catalyst under solvent-free conditions
    Lu, J
    Yang, BQ
    Bai, YJ
    SYNTHETIC COMMUNICATIONS, 2002, 32 (24) : 3703 - 3709
  • [34] A novel and efficient synthesis of nitriles from aldehydes under solvent-free microwave irradiation conditions
    Lee, Jong Chan
    Yoon, Jae Man
    Baek, Jong Wook
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2007, 28 (01) : 29 - 30
  • [35] Synthesis of 1,4-dithiocarbonyl piperazines under microwave irradiation in solvent-free conditions
    Gupta, M
    Paul, S
    Gupta, R
    SYNTHETIC COMMUNICATIONS, 2001, 31 (01) : 53 - 59
  • [36] Synthesis of metallophthalocyanines using microwave irradiation under solvent free and reflux conditions
    Safari, N
    Jamaat, PR
    Pirouzmand, M
    Shaabani, A
    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2004, 8 (10) : 1209 - 1213
  • [37] Solvent-free synthesis of sulfonephthaleins, sulfonefluoresceins and fluoresceins under microwave irradiation
    Cihelník, S
    Stibor, I
    Lhoták, P
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2002, 67 (12) : 1779 - 1789
  • [38] Solvent-free synthesis of substituted phenoxyacetic acids under microwave irradiation
    Nagy, G
    Filip, SV
    Surducan, E
    Surducan, V
    SYNTHETIC COMMUNICATIONS, 1997, 27 (21) : 3729 - 3736
  • [39] Rapid solvent-free synthesis of aromatic hydrazides under microwave irradiation
    Jain, Asheesh K.
    Gupta, Pradeep K.
    Ganesan, K.
    Pande, Ambuja
    Malhotra, R. C.
    DEFENCE SCIENCE JOURNAL, 2007, 57 (02) : 267 - 270
  • [40] Solvent-Free Synthesis of Substituted Phenoxyacetic Acids under Microwave Irradiation
    Nagy, G.
    Filip, S. V.
    Surducan, E.
    Surducan, V.
    Synthetic Communications, 27 (21):
12345