Synthesis of R-(-)-2-ethyl-N-benzyl (monoaza-15-crown-5) and the crystal structure of its sodium perchlorate complex

被引：14
|
作者：
Özbey, S
Hosgören, H
Turgut, Y
Topal, G
机构：
[1] Hacettepe Univ, Fac Engn, Dept Engn Phys, TR-06532 Ankara, Turkey
[2] Univ Dicle, Fac Arts & Sci, Dept Chem, TR-21280 Diyarbakir, Turkey
[3] Univ Dicle, Fac Educ, Dept Chem, TR-21280 Diyarbakir, Turkey
来源：
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2001年 / 39卷 / 3-4期
关键词：
chiral crown ether; crystal structure; monoaza-15-crown-5; sodium complex;
D O I：
10.1023/A:1011193009853
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new complex of a chiral monoaza-crown ether, [R-(-)-2-ethyl-N-benzyl-4,7,10,13-tetraoxa-1-azacyclopentadeceane) NaClO4], has been prepared and studied by x-ray diffraction. The compound crystallizes in space group P2(1) with cell dimensions a = 9.480(1), b = 15.978(2), c = 15.816(2) Angstrom, beta = 105.51(1)degrees, Z = 4. The final R value is 0.055 for 2711 observed reflections and 540 parameters. There are two molecules in the asymmetric unit labelled A and B. The sodium ion is hexacoordinated. The average values for the Na-O-eth (etheric) distances are 2.364(6), 2.317(7) Angstrom and the Na-N distances are 2.679(6), 2.611(7) Angstrom; the Na-O(ClO4) contacts are 2.497(7) and 2.257(10) Angstrom, for A and B, respectively.
引用
收藏
页码：315 / 320
页数：6
相关论文
共 50 条
  • [31] Tris{2-[(5-fluorosalicylidene)amino]ethyl}amine and its manganese(III) complex: Synthesis, characterization, crystal structures, and catalytic property
    Wei, Fen-Yan
    INORGANIC AND NANO-METAL CHEMISTRY, 2017, 47 (04) : 603 - 607
  • [32] Synthesis and Crystal Structure of 〔Na(N-（p-chlorophenyl）aza-15-crown-5)-（Et2O）〕2 (Na2W0.5Mo7.5O26)
    LU Xiao-Minga
    LIU Shun-Chenga (Department of Chemistry
    结构化学, 1997, (01) : 1 - 5
  • [33] Synthesis and crystal structure of (R, 4R)-3-[(N-benzyl-N-hydroxy-amino)-(1H-indol-3-yl)-methyl]-oxazolidin-2-one
    David, M
    Denis, JN
    Philouze, C
    Durif, A
    Vallée, Y
    COMPTES RENDUS CHIMIE, 2004, 7 (01) : 41 - 44
  • [34] Synthesis and Crystal Structure of a Ni(II) Complex of 2′-[4-N,N′-(Dimethylaminobenzylidene)]-3,5-dihydroxybenzoylhydrazide and Its Spectral Properties
    Jia Wen-Ping
    Yang Jian-Guo
    Li Fang
    Pan Fu-You
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 28 (12) : 1635 - 1639
  • [35] Synthesis, structure and SAR study on sulfonylurea compounds .5. Crystal and molecular structure of N-[2-(4-ethyl)triazinyl]-2-nitrobenzene sulfonylurea
    Li, ZM
    Liu, J
    Wang, X
    Yuan, MX
    Lai, CM
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1997, 18 (05): : 750 - 752
  • [36] Synthesis and Crystal Structure of 5,7-Dimethoxy-2-phenylquinolin-4-yl Phenyloxy (N-L-Alanine ethyl ester) Phosphoramidate
    袁金伟
    陈晓岚
    屈凌波
    朱玉
    黄小莹
    赵玉芬
    Chinese Journal of Structural Chemistry, 2009, (04) : 498 - 502
  • [37] Synthesis and Crystal Structure of 3′-Ethyl 5′-Methyl 1-Benzyl-4′-methyl-2-oxo-3′,4′-dihydrospiro-[indoline-3,2′-pyrrole]-3′,5′-dicarboxylate
    郑胡飞
    孟祥锁
    袁伟
    石德清
    Chinese Journal of Structural Chemistry, 2014, (06) : 871 - 875
  • [38] Synthesis and Crystal Structure of 3′-Ethyl 5′-Methyl 1-Benzyl-4′-methyl-2-oxo-3′,4′-dihydrospiro-[indoline-3,2′-pyrrole]-3′,5′-dicarboxylate
    Zheng Hu-Fei
    Meng Xiang-Suo
    Yuan Wei
    Shi De-Qing
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33 (06) : 871 - 875
  • [39] Synthesis and Crystal Structure of 5,7-Dimethoxy-2-phenylquinolin-4-yl Phenyloxy (N-L-Alanine ethyl ester) Phosphoramidate
    Yuan Jin-Wei
    Chen Xiao-Lan
    Qu Ling-Bo
    Zhu Yu
    Huang Xiao-Ying
    Zhao Yu-Fen
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 28 (04) : 498 - 502
  • [40] Synthesis and crystal structure of complex Cu[C5H3N(CCH3 = N-C6H5)2]2(PF6)2 and its kinetics of thermal decomposition
    Jiang, YM
    Tan, LF
    Yin, XJ
    Zhong, XX
    Zhang, SH
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2002, 18 (08) : 802 - 806
12345