On the oxidation behavior of ZrB2-SiC-VC composites

被引:6
作者
Arab, Seyed Mohammad [1 ]
Asl, Mehdi Shahedi [1 ]
Kakroudi, Mahdi Ghassemi [2 ]
Salahimehr, Behnam [2 ]
Mahmoodipour, Kosar [2 ]
机构
[1] Univ Mohaghegh Ardabili, Dept Mech Engn, Ardebil, Iran
[2] Univ Tabriz, Dept Mat Sci & Engn, Tabriz, Iran
关键词
hot pressing; oxidation; UHTCs; ZrB2-SiC-VC composite; MECHANICAL-PROPERTIES; IN-SITU; DENSIFICATION; RESISTANCE; ZIRCONIUM; ZRB2;
D O I
10.1111/ijac.13858
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this study, near-fully dense ZrB2-SiC-VC (75-20-5 vol%) composite was manufactured through hot pressing at 1850 degrees C under the pressure of 40 MPa for 60 min. Then the oxidation examination of the composite was carried out under different durations and temperatures. The microstructure and phase evolution after hot pressing and oxidation processes were examined by scanning electron microscopy, and X-ray diffractometry. The VC addition led to the formation of ZrC and VSi2 phases, which assisted the densification of the composite by removing ZrO2 from the particles' surface. The oxides of ZrO2, SiO2, ZrSiO4, V2O5, and VO2 formed distinct layers on the sample during the oxidation at 1700 degrees C for 4 h with a parabolic regimen and activation energy of 177.5 kJ/mol.
引用
收藏
页码:2306 / 2313
页数:8
相关论文
共 35 条
[1]  
Abdolahpour Salari M., 2021, Syn. Sint, V1, P48, DOI [10.53063/synsint.2021.119, DOI 10.53063/SYNSINT.2021.119]
[2]  
Bahararjmand Z., 2021, Syn. Sint, V1, P34, DOI [10.53063/ synsint.2021.1113, DOI 10.53063/SYNSINT.2021.1113, 10.53063/synsint.2021.1113]
[3]   Shrinkage, hardness and fracture toughness of ternary ZrB2-SiC-HfB2 composite with different amount of HfB2 [J].
Balak, Zohre .
MATERIALS CHEMISTRY AND PHYSICS, 2019, 235
[4]   Molten salt synthesis of in-situ TiC coating on graphite flakes [J].
Behboudi, Fatemeh ;
Kakroudi, Mahdi Ghassemi ;
Vafa, Nasser Pourmohammadie ;
Faraji, Mostafa ;
Milani, Sahar Sajjadi .
CERAMICS INTERNATIONAL, 2021, 47 (06) :8161-8168
[5]   Refractory diborides of zirconium and hafnium [J].
Fahrenholtz, William G. ;
Hilmas, Gregory E. ;
Talmy, Inna G. ;
Zaykoski, James A. .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2007, 90 (05) :1347-1364
[6]   Thermodynamic analysis of ZrB2-SiC oxidation:: Formation of a SiC-depleted region [J].
Fahrenholtz, William G. .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2007, 90 (01) :143-148
[7]  
FarahBakhsh I., 2021, Syn. Sint, V1, P99, DOI [10.53063/synsint.2021.1231, DOI 10.53063/SYNSINT.2021.1231]
[8]   Densification of ZrB2-based composites and their mechanical and physical properties: A review [J].
Guo, Shu-Qi .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2009, 29 (06) :995-1011
[9]   Effects of VC additives on densification and elastic and mechanical properties of hot-pressed ZrB2-SiC composites [J].
Guo, Shuqi .
JOURNAL OF MATERIALS SCIENCE, 2018, 53 (06) :4010-4021
[10]   Oxidation resistance and strength retention of ZrB2-SiC ceramics [J].
Guo, Wei-Ming ;
Zhang, Guo-Jun .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2010, 30 (11) :2387-2395