Reactive spin state dependent enantiospecific photocyclization of axially chiral α-substituted acrylanilides

被引：38

作者：

Ayitou, Anoklase Jean-Luc ^{[1
]}

Sivaguru, J. ^{[1
]}

机构：

[1] N Dakota State Univ, Dept Chem & Biochem, Fargo, ND 58108 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 09期

基金：

美国国家科学基金会;

关键词：

PHOTOCHEMISTRY; AMIDES; MEMORY;

D O I：

10.1039/c0cc04416d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The enantiomeric ratio (e.r.) in the 3,4-dihydroquinolin-2-one photoproduct during 6 pi-photocyclization of alpha-substituted axially chiral ortho-tert-butyl-acrylanilides depends on the nature of the reactive spin state (singlet or triplet), where the singlet-spin state reactivity gives a racemic mixture and the triplet reactivity gives an e.r. value >95 : 5.

引用

页码：2568 / 2570

页数：3

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