Electrooxidation of Quercetin at Polycrystalline Pt Electrode

被引:0
|
作者
Pierozynski, Boguslaw [1 ]
Zielinska, Danuta [1 ]
机构
[1] Univ Warmia & Mazury, Fac Environm Management & Agr, Dept Chem, PL-10957 Olsztyn, Poland
来源
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2010年 / 5卷 / 10期
关键词
Quercetin electrooxidation; CH3OH electrooxidation; Pt electrode poisoning; impedance spectroscopy; ELECTROCHEMICAL-BEHAVIOR; OXIDATION; IMPEDANCE; METHANOL; CATALYSTS; ONION; ACID;
D O I
暂无
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The present paper reports cyclic voltammetry and a. c. impedance spectroscopy studies on electrooxidation of quercetin (3,3',4',5,7-pentahydroxyflavone) molecule at polycrystalline Pt electrode surface in 0.1 M sodium acetate - acetic acid buffer in 75 % methanol solution. The significance of this work is demonstrated through the application of a highly-catalytic platinum electrode, which is well-known to be capable of electrochemically oxidizing methanol under similar conditions. In addition, all impedance-derived and associated charge-transfer resistance, and capacitance parameters are discussed, especially in relation to those previously presented for oxidation of quercetin at glassy carbon electrode.
引用
收藏
页码:1507 / 1515
页数:9
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