Scanning tunneling microscopy and molecular orbital calculation of thymine and adenine molecules adsorbed on the Si(100)2x1 surface

被引：18

作者：

Kasaya, M ^{[1
]}

Tabata, H ^{[1
]}

Kawai, T ^{[1
]}

机构：

[1] OSAKA UNIV, INST SCI & IND RES, OSAKA 567, JAPAN

来源：

SURFACE SCIENCE | 1996年 / 357卷 / 1-3期

关键词：

biological molecules nucleic acids; chemisorption; electron density; excitation spectra calculations; scanning tunneling microscopy; silicon;

D O I：

10.1016/0039-6028(96)00092-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The nucleic acid base molecules adenine and thymine adsorbed on Si(100)2 x 1 surfaces have been imaged by scanning tunneling microscopy (STM). The molecular images exhibit distinct shapes corresponding to the expected shapes for adenine and thymine. Semi-empirical molecular orbital calculations reveal the local surface density of states for the adsorbed molecules on the Si surface. These calculated features and adsorption sites are in good agreement with the molecular images observed in STM.

引用

页码：195 / 201

页数：7

共 14 条

[1]

[Anonymous], J AM CHEM SOC

[2] PREDICTING STM IMAGES OF MOLECULAR ADSORBATES [J].