Diastereoselective synthesis of 1-aryl-2-amino-cyclopropane carboxylates

被引：18

作者：

Melby, Trude ^{[1
]}

Hughes, Rachael Anne ^{[1
]}

Hansen, Tore ^{[1
]}

机构：

[1] Univ Oslo, Dept Chem, N-0315 Oslo, Norway

来源：

SYNLETT | 2007年 / 14期

关键词：

cyclopropanation; diastereoselective; rhodium; diazoacetates; amino-cyclopropanes;

D O I：

10.1055/s-2007-985587

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Methyl 1-aryl-2-amino-cyclopropane carboxylates have been readily synthesized in high yields by Rh-catalyzed decomposition of aryldiazoacetates in the presence of N-vinylphthalimide. The reaction is highly trans-selective.

引用

页码：2277 / 2279

页数：3

共 15 条

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