Volumetric, Refractometric, and Excess Properties of Glycylglycine in Aqueous FeCl2 Solution at Temperatures T = (288.15 to 318.15) K

被引:11
作者
Santosh, M. S. [1 ]
Bhat, D. Krishna [1 ]
Bhatt, Aarti S. [1 ]
机构
[1] Natl Inst Technol Karnataka, Dept Chem, Div Phys Chem, Mangalore 575025, India
关键词
MOLAR ENTHALPIES; AMINO-ACIDS; ADIABATIC COMPRESSIBILITIES; ALKAN-1-OLS C-1-C-6; REFRACTIVE-INDEXES; PLUS WATER; EQUATION; DENSITIES; MIXTURES; METHANOL;
D O I
10.1021/je100151b
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities and refractive indices have been measured for glycylglycine in aqueous FeCl2 solution as a function of concentration at T = (288.15 to 318.15) K. The apparent molar volumes and partial molar volumes were obtained from these density data. The limited partial molar expansivities have been calculated from the temperature dependence of the partial molar volume. The molar refractions were calculated from the experimental refractive index values for the studied mixture. The excess volumes and molar refractions were also calculated. The results are discussed in terms of molecular interactions.
引用
收藏
页码:4048 / 4053
页数:6
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