Coupling analysis of macroscopic and microscopic behaviour in highly consolidated Na-laponite clays

被引:36
作者
Qi, Y [1 ]
AlMukhtar, M [1 ]
Alcover, JF [1 ]
Bergaya, F [1 ]
机构
[1] UNIV ORLEANS,CNRS,CTR RECH,DIV MAT,F-45071 ORLEANS 2,FRANCE
关键词
Na-laponite; clay; axial stress; BET; XRD; TGA; microstructural parameters;
D O I
10.1016/S0169-1317(96)00016-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The great importance of problems related to the storage of chemical and radioactive wastes requires better understanding of the behaviour of the host media. In the case of clay soils, their behaviour is controlled by their microtexture, their mineral composition and their physico-chemical properties (interaction between interstitial fluid and solid matrix). In this paper, the analysis of the behaviour of consolidated synthetic model clay Na-laponite is presented. Tests are conducted on samples submitted to axial stress for the determination of the distribution of pore space and the type of interstitial water. Analysis is based on data given by different techniques: BET, mercury intrusion, X-ray diffraction and thermogravimetric analysis. The basal spacing d(001) and the water content decrease respectively from 2.5 nm to 1.6 nm and from 140% to 63% when the axial mechanical stress increases from 1 to 10 MPa. Results obtained would allow to take into account the relationships between the applied stress on the samples and the basal spacing, the number of water layers and the water content in the formulation of numerical modelling of the macroscopic behaviour.
引用
收藏
页码:185 / 197
页数:13
相关论文
共 15 条
[1]   Dehydration of Cu-hectorite: Water isotherm, XRD, and EPR studies [J].
AnnabiBergaya, F ;
EstradeSzwarckopf, H ;
VanDamme, H .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (10) :4120-4126
[2]   ADSORPTION OF ALCOHOLS BY SMECTITES .1. DISTINCTION BETWEEN INTERNAL AND EXTERNAL SURFACES [J].
ANNABIBERGAYA, F ;
CRUZ, MI ;
GATINEAU, L ;
FRIPIAT, JJ .
CLAY MINERALS, 1979, 14 (04) :249-258
[3]  
[Anonymous], MATER RES SOC SYMP P
[4]  
BALDI G, 1988, CAN GEO J, V5, P807
[5]  
Bolt G.H., 1956, GEOTECHNIQUE, V6, P86, DOI DOI 10.1680/GEOT.1956.6.2.86
[6]   USE OF THE CRYOSCAN APPARATUS FOR OBSERVATION OF FREEZE-FRACTURED PLANES OF A SENSITIVE QUEBEC CLAY IN SCANNING ELECTRON-MICROSCOPY [J].
DELAGE, P ;
TESSIER, D ;
MARCELAUDIGUIER, M .
CANADIAN GEOTECHNICAL JOURNAL, 1982, 19 (01) :111-114
[7]   THE EFFECTIVE STRESS CONCEPT IN SATURATED SAND CLAY BUFFER [J].
GRAHAM, J ;
OSWELL, JM ;
GRAY, MN .
CANADIAN GEOTECHNICAL JOURNAL, 1992, 29 (06) :1033-1043
[8]  
HUECKEL T, 1991, INT WORKSH STRESS PA
[9]  
Mitchell J.K., 2005, FUNDAMENTALS SOIL BE, V3
[10]  
MORVAN M, 1993, THESIS U PARIS 6