Ring-size controllable metallamacrocycles as building blocks for the construction of microporous metal-organic frameworks

被引：44

作者：

Jiang, Zhi-Qiang ^{[1
,2
]}

Jiang, Gui-Yuan ^{[1
]}

Wang, Fei ^{[2
]}

Zhao, Zhen ^{[1
]}

Zhang, Jian ^{[2
]}

机构：

[1] China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 30期

关键词：

NETWORKS;

D O I：

10.1039/c2cc17256a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Presented here is a new strategy for the synthesis of metallamacrocycles (MC[n]) with different ring-size and guest selectivity via integrating a flexible trinuclear metal unit and a bridging organic ligand, and further body-centered cubic packing of these MCs results in the formation of three microporous MOFs for potential application in gas storage.

引用

页码：3653 / 3655

页数：3

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