Synthesis and Characterization of Sulfone Containing Polymethylmethacrylate via Atom Transfer Radical Polymerization

被引：0

作者：

Canak, Tuba Cakir ^{[1
]}

Celioglu, Selcan ^{[1
]}

Erbay, Betul Turel ^{[1
]}

Serhatli, I. Ersin ^{[1
]}

机构：

[1] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

来源：

JOURNAL OF POLYMER MATERIALS | 2015年 / 32卷 / 02期

关键词：

ATRP; Initiator; Polymethylmethacrylate; Sulfone containing; PROTON-EXCHANGE MEMBRANES; BLOCK-COPOLYMERS; BISPHENOL-S; AMORPHOUS COPOLYESTERS; POLYIMIDE COPOLYMERS; FORMALDEHYDE RESIN; FACILE APPROACH; FUEL-CELLS; ATRP; ACID;

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of polymethylmethacrylate (pMMA) was realized with newly synthesized difunctional initiator, bis[4-(beta-(2-bromopropanoate) ethoxy) phenyl]sulphone (BrEPS) in the presence of copper bromide (CuBr) and N, N, N', N", N"-pentamethyl-diethylenetriamine (PMDETA) by using atom transfer radical polymerization (ATRP). Sulphone group containing initiator was prepared by esterification of bis[4-(beta-hydroxyethoxy)phenyl] sulfone (HEPS). Both initiator and polymers were characterized by H-1-NMR spectroscopy, gel permeation chromatography (GPC), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The ATRP was supported by an increase in the molecular weight of the forming polymers and also by their monomodal molecular weight distribution. Pendulum hardness tests on films of synthesized polymers indicated higher degree of hardness than that of pure pMMA.

引用

页码：113 / 126

页数：14

共 52 条

[1]

Agudelo N. A., 2014, J POLYM SCI A

[2] Atom transfer radical polymerization of methylmethacrylate and styrene initiated by 3,5-bis(perfluorobenzyloxy)benzyl 2-bromopropanoate [J].

Canak, Tuba Cakir ;

Selcukoglu, Mukaddes ;

Hamuryudan, Esin ;

Serhatli, I. Ersin .

JOURNAL OF APPLIED POLYMER SCIENCE, 2012, 124 (02) :1683-1694

[3] Synthesis of cyclohexanone formaldehyde resin-methylmethacrylate block-graft copolymers via ATRP [J].

Canak, Tuba Cakir ;

Kizilcan, Nilgun ;

Serhatli, I. Ersin .

JOURNAL OF APPLIED POLYMER SCIENCE, 2012, 123 (05) :2628-2635

[4] Synthesis of Acetophenone Formaldehyde Resin Containing ABA Type Block Copolymers by ATRP [J].

Canak, Tuba Cakir ;

Kizilcan, Nilgun ;

Serhatli, I. Ersin .

JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 119 (01) :183-189

[5] ATRP from a norbornenyl-functionalized initiator:: Balancing of complementary reactivity for the preparation of α-norbornenyl macromonomers/ω-haloalkyl macroinitiators [J].

Cheng, C ;

Khoshdel, E ;

Wooley, KL .

MACROMOLECULES, 2005, 38 (23) :9455-9465

[6] Synthesis and characterization of pH/temperature-sensitive block copolymers via atom transfer radical polymerization [J].

Dayananda, Kasala ;

Pi, Bong Soo ;

Kim, Bong Sup ;

Park, Tae Gwan ;

Lee, Doo Sung .

POLYMER, 2007, 48 (03) :758-762

[7] Enhanced conductivity in morphologically controlled proton exchange membranes: Synthesis of macromonomers by SFRP and their incorporation into graft polymers [J].

Ding, JF ;

Chuy, C ;

Holdcroft, S .

MACROMOLECULES, 2002, 35 (04) :1348-1355

[8] Sulfonated naphthalene dianhydride based polyimide copolymers for proton-exchange-membrane fuel cells II. Membrane properties and fuel cell performance [J].

Einsla, BR ;

Kim, YS ;

Hickner, MA ;

Hong, YT ;

Hill, ML ;

Pivovar, BS ;

McGrath, JE .

JOURNAL OF MEMBRANE SCIENCE, 2005, 255 (1-2) :141-148

[9] Sulfonated naphthalene dianhydride based polyimide copolymers for proton-exchange-membrane fuel cells. I. Monomer and copolymer synthesis [J].

Einsla, BR ;

Hong, YT ;

Kim, YS ;

Wang, F ;

Gunduz, N ;

Mcgrath, JE .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (04) :862-874

[10] Step-growth polymers as macroinitators for ''living'' radical polymerization: Synthesis of ABA block copolymers [J].

Gaynor, SG ;

Matyjaszewski, K .

MACROMOLECULES, 1997, 30 (14) :4241-4243

← 1 2 3 4 5 6 →