New D-D-π-A-type indol-triarylamine sensitizers for efficient dye-sensitized solar cells

被引:12
作者
Yuan, Rui [3 ]
Liu, Zhen-tao [2 ]
Wan, Yu [1 ]
Liu, Yun [1 ]
Wang, Yuan-jiang [1 ]
Ge, Wen-hui [1 ]
Fang, Yue [1 ]
Zhou, Sheng-liang [1 ]
Han, Xiang-en [2 ]
Zhang, Peng [1 ]
Wu, Hui [1 ]
机构
[1] Jiangsu Normal Univ, Sch Chem & Chem Engn, State Key Lab Cultivat Construct Base Biotechnol, Xuzhou 221116, Peoples R China
[2] China Univ Min & Technol, Sch Chem Engn, Xuzhou 221000, Peoples R China
[3] Lanzhou Univ, Sch Life Sci, Inst Biochem & Mol Biol, Lanzhou 730000, Peoples R China
关键词
Indol-triarylamine sensitizers; D-D-pi-A dyes; Theoretical calculations; Synthesis; Optical and electrochemical properties; ORGANIC-DYES; CONVERSION-EFFICIENCY; DESIGN; DONOR;
D O I
10.1016/j.synthmet.2016.01.024
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A series of new D-D-pi-A-type indol-triarylamine sensitizers were designed and evaluated by the theoretical calculations. Based on the exciting results of calculation, they were synthesized and used as the sensitizers for DSSCs. The results indicated that the incorporation of indole derivatives and TPA skeleton made the new dyes possessing excellent non-planarity, optical and electrochemical properties, thermo-stability and relative high melting.point and therefore performed well as expected as the dyes of a DSSC. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:21 / 27
页数:7
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