An Isolable Mixed P,S-Bis(ylide) as an Asymmetric Carbon Atom Source

被引：32

作者：

Dellus, Nicolas ^{[2
]}

Kato, Tsuyoshi ^{[2
]}

Bagan, Xavier ^{[3
]}

Saffon-Merceron, Nathalie ^{[1
]}

Branchadell, Vicenc ^{[3
]}

Baceiredo, Antoine ^{[2
]}

机构：

[1] Univ Toulouse, UPS, SFTCM FR2599, F-31062 Toulouse 9, France

[2] CNRS, LHFA UMR 5069, F-31062 Toulouse 9, France

[3] Univ Autonoma Barcelona, Dept Quim, Bellaterra 08193, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 38期

关键词：

carbon; phosphorus; reaction intermediates sulfur; ylides; COORDINATION CHEMISTRY; CARBODIPHOSPHORANES; HEXAPHENYLCARBODIPHOSPHORANE; ALKYLIDENECARBENES; TRIBOLUMINESCENCE; PHOSPHONIUM; KETONES; YLIDES;

D O I：

10.1002/anie.201002833

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heart of carbon: The first stable asymmetric bis(ylide), N,N'-(iPr 2NCH2CH2NiPr) (Ph) P-C-SPh2, has been isolated (see picture; C black, N gray). The presence of the two different ligands causes this carbon (0) complex to behave as an asymmetric atomic carbon source. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6798 / 6801

页数：4

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