Au@Cu(II)-MOF: Highly Efficient Bifunctional Heterogeneous Catalyst for Successive Oxidation-Condensation Reactions

被引：107

作者：

Wang, Jing-Si ^{[1
]}

Jin, Fa-Zheng ^{[1
]}

Ma, Hui-Chao ^{[1
]}

Li, Xiao-Bo ^{[1
]}

Liu, Ming-Yang ^{[1
]}

Kan, Jing-Lan ^{[1
]}

Chen, Gong-Jun ^{[1
]}

Dong, Yu-Bin ^{[1
]}

机构：

[1] Shandong Normal Univ, Collaborat Innovat Ctr Functionalized Probes Chem, Coll Chem Chem Engn & Mat Sci, Minist Educ,Key Lab Mol & Nano Probes, Jinan 250014, Peoples R China

来源：

INORGANIC CHEMISTRY | 2016年 / 55卷 / 13期

关键词：

METAL-ORGANIC FRAMEWORKS; SUPPORTED GOLD NANOPARTICLES; SOLVENT-FREE OXIDATION; AEROBIC OXIDATION; BENZYL ALCOHOL; SELECTIVE OXIDATION; AU NANOPARTICLES; MOLECULAR-OXYGEN; CO OXIDATION; REDUCTION;

D O I：

10.1021/acs.inorgchem.6b00925

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new composite Au@Cu(II)-MOF catalyst has been synthesized via solution impregnation and full characterized by HRTEM, SEM-EDS, XRD, gas adsorption-desorption, XPS, and ICP analysis. It has been shown here that the Cu(II)-framework can be a useful platform to stabilize and support gold nanoparticles (Au NPs). The obtained Au@Cu(II)-MOF exhibits a bifunctional catalytic behavior and is able to promote selective aerobic benzyl alcohol oxidation-Knoevenagel condensation in a stepwise way.

引用

页码：6685 / 6691

页数：7

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