Laser ablation: A new technique for the preparation of metal-organic frameworks Cu3(BTC)2(H2O)3

被引：24
|
作者：
Campello, S. L. [1 ]
Gentil, G. [2 ]
Junior, S. A. [2 ]
de Azevedo, W. M. [2 ]
机构：
[1] Univ Fed Pernambuco, Ctr Acad Agreste, BR-55014900 Recife, PE, Brazil
[2] Univ Fed Pernambuco, Dept Quim Fundamental, BR-50670901 Recife, PE, Brazil
来源：
MATERIALS LETTERS | 2015年 / 148卷
关键词：
Laser ablation; Metal-organic framework; Non-conventional synthesis; IONOTHERMAL SYNTHESIS; GOLD NANOPARTICLES; COORDINATION POLYMER; SILVER NANOPARTICLES; SIZE CONTROL; LIQUID; BTC; GENERATION; SEPARATION; STABILITY;
D O I：
10.1016/j.matlet.2015.01.159
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
This paper presents a chemical bottom-up synthesis of highly crystalline sub micro structured metal organic framework Cu-3(BTC)(2)(H2O)(3) (HKUST-1, BTC=benzene-1,3,5-tricarboxylate) prepared for the first time by a Laser ablation technique in liquid environment. The experiment consists of the ablation of a Cu metal target in a solution of DMF/H2O (1:1) containing benzene 1,3,5, benzene tricarboxilic acid and NaNO3 with a high power second harmonic of a Nd:YAG laser. The X-ray and SEM measurements showed that high crystalline Cu-3(BTC)(2)(H2O)(3) with octahedral morphology and dimensions in the range of 200 nm to 2 mu m were obtained in a high yield. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：200 / 203
页数：4
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