Structure and magnetic properties of Zn-Fe cyanide

被引：18

作者：

Ng, CW ^{[1
]}

Ding, J

Gan, LM

机构：

[1] Natl Univ Singapore, Dept Mat Sci, Singapore 119260, Singapore

[2] Natl Univ Singapore, Dept Chem, Singapore 119260, Singapore

[3] Natl Univ Singapore, Inst Mat & Res Engn, Singapore 119260, Singapore

来源：

JOURNAL OF PHYSICS D-APPLIED PHYSICS | 2001年 / 34卷 / 08期

关键词：

D O I：

10.1088/0022-3727/34/8/309

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Zinc II hexacyanoferrate III, Zn-1.5[Fe(CN)(6)]. 6H(2)O, was prepared by coprecipitation method. The precipitated powder possessed a face-centred cubic structure with a lattice parameter of 10.32 Angstrom. Phase transformation in this cyanide compound was encountered after heat treatment at a temperature at 75 degreesC or above, from a face-centred cubic to a monoclinic structure. The finding of these different structures could help one to have a better understanding of the magnetic properties of the compound after being subjected to different stages of thermal treatment.

引用

页码：1188 / 1192

页数：5

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